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Träfflista för sökning "WFRF:(Matic Aleksandar 1968) srt2:(2010-2014);pers:(Aguilera Medina Luis 1983)"

Sökning: WFRF:(Matic Aleksandar 1968) > (2010-2014) > Aguilera Medina Luis 1983

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1.
  • Lombardo, L., et al. (författare)
  • In-situ gelled electrolyte for lithium battery: Electrochemical and Raman characterization
  • 2014
  • Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753. ; 245, s. 232-235
  • Tidskriftsartikel (refereegranskat)abstract
    • n this paper we report a polymer lithium cell using a PVdF-based, gel-type electrolyte formed in-situ during cell assembly. The gel electrolyte formation is monitored prior to cell assembly by electro-chemical impedance spectroscopy and by Raman spectroscopy in order to determine the characteristics of the lithium salt diffusion into the gel-membrane. The results show an efficient gel formation and a fast lithium salt diffusion, this finally resulting in an optimized behaviour in a lithium cell using a high voltage spinel-type cathode. We believe that the results here reported may contribute to the enhancement of the safety of lithium batteries. (C) 2013 Elsevier B.V. All rights reserved.
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2.
  • Nordström, Jonas, 1980, et al. (författare)
  • Effect of Lithium Salt on the Stability of Dispersions of Fumed Silica in the Ionic Liquid BMImBF4
  • 2012
  • Ingår i: Langmuir. - : American Chemical Society (ACS). - 1520-5827 .- 0743-7463. ; 28:9, s. 4080-4085
  • Tidskriftsartikel (refereegranskat)abstract
    • We have investigated the stability and the interactions in dispersions of colloidal fumed silica, Aerosil 200, and the ionic liquid 1-butyl-3-methylimidazolium tetraflouroborate (BMImBF4) as a function of Li-salt concentration (LiBF4). Photon correlation spectroscopy was used to study the aggregation behavior at low silica concentration and Raman spectroscopy was used to investigate the interactions in the ionic liquid and with the silica surface. We find that the addition of LiBF4 increases the stability of the dispersions, with smaller agglomerates of silica particles and higher gelation concentrations in the presence of Li-salt. The increased stability with the addition of Li-salt is explained by the formation of a more stable solvation layer, where Li-ions accumulate on the surface. This leads to an increased interaction between lithium ions and the BF4- anions in the solvation layer as seen by Raman spectroscopy. Upon gelation the Li-ions are expelled from the surface as hydrogen bonding between the silica particles are formed. For both neat BMImBF4 and Li-salt doped BMImBF4/silica dispersions a weak gel phase was found preceding the formation of a strong gel at slightly higher silica concentrations.
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Matic, Aleksandar, 1 ... (2)
Aguilera Medina,... (2)Ta bort avgränsningen
Navarra, M.A. (1)
Panero, S. (1)
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