| 1. |
- Kehoe, Laura, et al.
(författare)
-
Make EU trade with Brazil sustainable
- 2019
-
Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 364:6438, s. 341-
-
Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)
|
|
| 2. |
- Wiedorn, Max O., et al.
(författare)
-
Megahertz serial crystallography
- 2018
-
Ingår i: Nature Communications. - : Nature Publishing Group. - 2041-1723. ; 9
-
Tidskriftsartikel (refereegranskat)abstract
- The new European X-ray Free-Electron Laser is the first X-ray free-electron laser capable of delivering X-ray pulses with a megahertz inter-pulse spacing, more than four orders of magnitude higher than previously possible. However, to date, it has been unclear whether it would indeed be possible to measure high-quality diffraction data at megahertz pulse repetition rates. Here, we show that high-quality structures can indeed be obtained using currently available operating conditions at the European XFEL. We present two complete data sets, one from the well-known model system lysozyme and the other from a so far unknown complex of a beta-lactamase from K. pneumoniae involved in antibiotic resistance. This result opens up megahertz serial femtosecond crystallography (SFX) as a tool for reliable structure determination, substrate screening and the efficient measurement of the evolution and dynamics of molecular structures using megahertz repetition rate pulses available at this new class of X-ray laser source.
|
|
| 3. |
- Soyama, Hitoshi, et al.
(författare)
-
Revealing the origins of vortex cavitation in a Venturi tube by high speed X-ray imaging
- 2023
-
Ingår i: Ultrasonics Sonochemistry. - 1350-4177. ; 101
-
Tidskriftsartikel (refereegranskat)abstract
- Hydrodynamic cavitation is useful in many processing applications, for example, in chemical reactors, water treatment and biochemical engineering. An important type of hydrodynamic cavitation that occurs in a Venturi tube is vortex cavitation known to cause luminescence whose intensity is closely related to the size and number of cavitation events. However, the mechanistic origins of bubbles constituting vortex cavitation remains unclear, although it has been concluded that the pressure fields generated by the cavitation collapse strongly depends on the bubble geometry. The common view is that vortex cavitation consists of numerous small spherical bubbles. In the present paper, aspects of vortex cavitation arising in a Venturi tube were visualized using high-speed X-ray imaging at SPring-8 and European XFEL. It was discovered that vortex cavitation in a Venturi tube consisted of angulated rather than spherical bubbles. The tangential velocity of the surface of vortex cavitation was assessed considering the Rankine vortex model.
|
|
| 4. |
- Palladino, Nicoletta, et al.
(författare)
-
Nanomaterials for combined stabilisation and deacidification of cellulosic materials - the case of iron-tannate dyed cotton
- 2020
-
Ingår i: Nanomaterials. - : MDPI AG. - 2079-4991. ; 10:5
-
Tidskriftsartikel (refereegranskat)abstract
- The conservation of textiles is a challenge due to the often fast degradation that results from the acidity combined with a complex structure that requires remediation actions to be conducted at several length scales. Nanomaterials have lately been used for various purposes in the conservation of cultural heritage. The advantage with these materials is their high efficiency combined with a great control. Here, we provide an overview of the latest developments in terms of nanomaterials-based alternatives, namely inorganic nanoparticles and nanocellulose, to conventional methods for the strengthening and deacidification of cellulose-based materials. Then, using the case of iron-tannate dyed cotton, we show that conservation can only be addressed if the mechanical strengthening is preceded by a deacidification step. We used CaCO3 nanoparticles to neutralize the acidity, while the stabilisation was addressed by a combination of nanocellulose, and silica nanoparticles, to truly tackle the complexity of the hierarchical nature of cotton textiles. Silica nanoparticles enabled strengthening at the fibre scale by covering the fibre surface, while the nanocellulose acted at bigger length scales. The evaluation of the applied treatments, before and after an accelerated ageing, was assessed by tensile testing, the fibre structure by SEM and the apparent colour changes by colourimetric measurements.
|
|
| 5. |
- Baglioni, M., et al.
(författare)
-
Nanostructured fluids from degradable nonionic surfactants for the cleaning of works of art from polymer contaminants
- 2014
-
Ingår i: Soft Matter. - : Royal Society of Chemistry (RSC). - 1744-6848 .- 1744-683X. ; 10:35, s. 6798-6809
-
Tidskriftsartikel (refereegranskat)abstract
- Nanostructured fluids containing anionic surfactants are among the best performing systems for the cleaning of works of art. Though efficient, their application may result in the formation of a precipitate, due to the combination with divalent cations that might leach out from the artifact. We propose here two new aqueous formulations based on nonionic surfactants, which are non-toxic, readily biodegradable and insensitive to the presence of divalent ions. The cleaning properties of water-nonionic surfactant-2-butanone (MEK) were assessed both on model surfaces and on a XIII century fresco that could not be cleaned using conventional methods. Structural information on nanofluids has been gathered by means of small-angle neutron scattering, dynamic light scattering and nuclear magnetic resonance with diffusion monitoring. Beside the above-mentioned advantages, these formulations turned out to be considerably more efficient in the removal of polymer coatings than those based on anionic surfactants. Our results indicate that the cleaning process most likely consists of two steps: initially, the polymer film is swollen by the MEK dissolved in the continuous domain of the nanofluid; in the second stage, surfactant aggregates come into play by promoting the removal of the polymer film with a detergency-like mechanism. The efficiency can be tuned by the composition and nature of amphiphiles and is promoted by working as close as possible to the cloud point of the formulation, where the second step proceeds at maximum rate.
|
|
| 6. |
- Futrzynski, Romain, 1988-
(författare)
-
Effect of drag reducing plasma actuators using LES
- 2017
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The work performed in this thesis explores new ways of reducing the drag of ground vehicles. Specifically, the effect of plasma actuators are investigated numerically with the intention to delay separation around a half-cylinder, a geometry chosen to represent a simplified A-pillar of a truck.The plasma actuators have to be included in turbulent flow simulations. Therefore, emphasis is first put on finding a numerical model that can reproduce the effect of the plasma without increasing the computational cost. This effect is modeled through a body force term added to the Navier-Stokes equations. To determine the strength and spatial extent of this body force, optimization was performed to minimize the difference between experimental and simulated profiles of plasma induced velocity. The plasma actuator model is thereafter used in Large Eddy Simulations (LES) of the flow around a half-cylinder at Reynolds number Re=65*10^3 and Re=32*10^3. Two types of actuation cases are performed. In the first case, a single actuator is used. In the second case, a pair of consecutive actuators are used, and their position on the half-cylinder is changed. It is found that a drag reduction of up to 10% is achievable. Moreover, the ideal location for actuation is determined to be near the separation point of the non-actuated flow. Finally, dynamic mode decomposition (DMD) is investigated as a tool to extract coherent dynamic structures from a turbulent flow field. The DMD is first used to analyze a channel flow where pulsations are imposed at a known frequency. It is found that DMD gives similar results to phase averaging done at the oscillation frequency. However, the presence of turbulence noise hinders the ability to identify modes at higher harmonics. The DMD is also used to post-process the half-cylinder flow case. There, it is found that the spectrum of the wake is broadband. Nevertheless, modes within distinct frequency ranges are found to be located in distinct spatial regions.
|
|
| 7. |
- Futrzynski, Romain, 1988-, et al.
(författare)
-
Numerical simulation of a plasma actuator on a half-submerged cylinder
- 2013
-
Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- In this paper Large Eddy Simulations are used to study the reduction of drag that can be achieved on a half-submerged cylinder by using a type of plasma actuator: the single dielectric barrier discharge. Two body force models, one based on an exponential decrease of the force away from the plasma, the other based on a simplified electric field between the electrodes, are compared to experimental values when the actuator is positioned at the apex of the cylinder in an otherwise quiescent environment. The cylinder is then put in a crossflow, and the exponential-based model, which gives the velocity profiles the closest to the experimental data, is used to simulate the effect of the plasma actuator on such a flow. The reduction in drag is changed as the position of the actuator is varied.
|
|
| 8. |
- Futrzynski, Romain, 1988-
(författare)
-
Drag reduction using plasma actuators
- 2015
-
Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis is motivated by the application of active flow control on the cabin of trucks, thereby providing a new means of drag reduction. Particularly, the work presented strives to identify how plasma actuators can be used to reduce the drag caused by the detachment of the flow around the A-pillars. This is achieved by conducting numerical simulations, and is part of a larger project that also includes experimental.The effect of plasma actuators is modeled through a body force, which adds very little computational cost and is suitable for implementation in most CFD solvers. The spatial distribution of this force is described by coefficients which have been optimized against experimental data, and the model was shown to be able to accurately reproduce the wall jet created by a single plasma actuator in a no-flow condition.A half cylinder geometry - a simplified geometry for the A-pillar of a truck - was used in a preliminary Large Eddy Simulation (LES) study that showed that the actuator alone, operated continuously, was not sufficient to achieve a significant reduction of the drag. Nevertheless, a significant drag reduction was obtained by simply increasing the strength of the body force to a higher value, showing that this type of actuation remains relevant for the reduction of drag.In the course of finding ways to improve the efficiency of the actuator, dynamic mode decomposition was investigated as a post-processing tool to extract structures in the flow. Such structures are identified by their spatial location and frequency, and might help to understand how the actuator should be used to maximize drag reduction. Thus a parallel code for dynamic mode decomposition was developed in order to facilitate the treatment of the large amounts of data obtained by LES. This code and LES itself were thereafter evaluated in the case of a pulsating channel flow. By using the dynamic mode decomposition it was possible to accurately extract oscillating profiles at the forcing frequency, although harmonics with lower amplitude compared to the turbulence intensity could not be obtained.
|
|
| 9. |
- Iselau, Frida, 1979, et al.
(författare)
-
Role of the aggregation behavior of hydrophobic particles in paper surface hydrophobation
- 2015
-
Ingår i: Colloids and Surfaces A: Physicochemical and Engineering Aspects. - : Elsevier BV. - 1873-4359 .- 0927-7757. ; 483, s. 264-270
-
Tidskriftsartikel (refereegranskat)abstract
- Three types of hydrophobic particles with different charge, i.e. cationic (SP+), anionic (SP-) and amphoteric (SPA) have been synthesized by emulsion polymerizations and evaluated in paper surface hydrophobation performance (frequently referred to as surface sizing). The surface sizing evaluation was done according to a well-established process, i.e. mixing of the particles with negatively charged starch followed by application in a conventional puddle size press using a fine paper grade containing calcium carbonate filler as model system. Prior to the application, the particles were characterized by light scattering and the surface charge was determined by particle charge density titrations and ζ-potential measurements. The SP+ particles were determined to be 30. nm in diameter while SP- and SPA particles were around 65. nm. Their colloidal behavior in the presence of anionic starch differed. The SP+ particles formed aggregates via bridging flocculation up to a charge ratio of 1:1 of starch:particles. At higher starch content the aggregates were partly redispersed. The SP- and SPA particles showed no sign of aggregation in the presence of anionic starch. In addition, the sizing performance of the different particles was evaluated by assessing the decrease of water uptake in a surface treated paper as well as water contact angle measurements on the paper surface. All three types of particles decreased the water penetration. However, the SP+/starch mixtures showed superior performance, which was attributed to a stronger sensitivity to the high electrolyte concentration usually found in the vicinity of the paper surface when the semi-soluble minerals composing the filler are exposed to water.
|
|
| 10. |
- Zelinka, Samuel L., et al.
(författare)
-
Interlaboratory study of the operational stability of automated sorption balances
- 2024
-
Ingår i: Adsorption. - 0929-5607.
-
Tidskriftsartikel (refereegranskat)abstract
- Automated sorption balances are widely used for characterizing the interaction of water vapor with hygroscopic materials. These instruments provide an efficient way to collect sorption isotherm data and kinetic data. A typical method for defining equilibrium after a step change in relative humidity (RH) is using a particular threshold value for the rate of change in mass with time. Recent studies indicate that commonly used threshold values yield substantial errors and that further measurements are needed at extended hold times as a basis to assess the accuracy of abbreviated equilibration criteria. However, the mass measurement accuracy at extended times depends on the operational stability of the instrument. Published data on the stability of automated sorption balances are rare. An interlaboratory study was undertaken to investigate equilibration criteria for automated sorption balances. This paper focuses on the mass, temperature, and RH stability and includes data from 25 laboratories throughout the world. An initial target for instrument mass stability was met on the first attempt in many cases, but several instruments were found to have unexpectedly large instabilities. The sources of these instabilities were investigated and greatly reduced. This paper highlights the importance of verifying operational mass stability of automated sorption balances, gives a method to perform stability checks, and provides guidance on identifying and correcting common sources of mass instability.
|
|
