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  • Parchenko, Sergii, et al. (author)
  • Orbital dynamics during an ultrafast insulator to metal transition
  • 2020
  • In: Physical Review Research. - : AMER PHYSICAL SOC. - 2643-1564. ; 2:2
  • Journal article (peer-reviewed)abstract
    • We present ultrafast resonant inelastic x-ray scattering (RIXS) experiments performed at the vanadium L edge to track changes in the electronic structure of V2O3, a classical Mott-Hubbard material. The probed orbital excitations within the d shell of the V ion show a sub-ps time response, which evolves at later times to a state that appears electronically indistinguishable from the high-temperature metallic state. For low excitation fluences, a transient recovery or delay is observed, which could be related to a transient dimerization of the V-V bonds. Our results demonstrate the great potential for RIXS spectroscopy to study the ultrafast orbital dynamics in strongly correlated materials.
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