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Sökning: WFRF:(Woodward C) > (2005-2009) > Naturvetenskap

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1.
  • Lynch, David K., et al. (författare)
  • NOVA V2362 CYGNI (NOVA CYGNI 2006): SPITZER, SWIFT, AND GROUND-BASED SPECTRAL EVOLUTION
  • 2008
  • Ingår i: Astronomical Journal. - 1538-3881 .- 0004-6256. ; 136:number 5, 2008 November, s. 1815-1827
  • Tidskriftsartikel (refereegranskat)abstract
    • Nova V2362 Cygni has undergone a number of very unusual changes. Ground-based spectroscopy initially revealed a normal sequence of events: the object faded and its near-infrared emission lines gradually shifted to higher excitation conditions until about day 100 when the optical fading reversed and the object slowly brightened. This was accompanied by a rise in the Swift X-ray telescope flux and a sudden shift in excitation of the visible and IR spectrum back to low levels. The new lower excitation spectrum revealed broad line widths and many P-Cygni profiles, all indicative of the ejection of a second shell. Eventually, dust formed, the X-ray brightness—apparently unaffected by dust formation—peaked and then declined, and the object faded at all wavelengths. The Spitzer dust spectra revealed a number of solid-state emission features that, at this time, are not identified.
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2.
  • Poulton, Alex J., et al. (författare)
  • Phytoplankton carbon fixation, chlorophyll-biomass and diagnostic pigments in the Atlantic Ocean
  • 2006
  • Ingår i: Deep-sea research. Part II, Topical studies in oceanography. - : Elsevier BV. - 0967-0645 .- 1879-0100. ; 53:14-16, s. 1593-1610
  • Tidskriftsartikel (refereegranskat)abstract
    • We have made daily measurements of phytoplankton pigments, size-fractionated (< 2 and > 2-mu m) carbon fixation and chlorophyll-a concentration during four Atlantic Meridional Transect (AMT) cruises in 2003-04. Surface rates of carbon fixation ranged from < 0.2-mmol C m(-3) d(-1) in the subtropical gyres to 0.2-0.5-mmol C m(-3) d(-1) in the tropical equatorial Atlantic. Significant intercruise variability was restricted to the subtropical gyres, with higher chlorophyll-a concentrations and carbon fixation in the subsurface chlorophyll maximum during spring in either hemisphere. In surface waters, although picoplankton (<-mu m) represented the dominant fraction in terms of both carbon fixation (50-70%) and chlorophyll-alpha (80-90%), nanoplankton (> 2-mu m) contributions to total carbon fixation (30-50%) were higher than to total chlorophyll-alpha (10-20%). However, in the subsurface chlorophyll maximum picoplankton dominated both carbon fixation (70-90%) and chlorophyll-alpha (70-90%). Thus, in surface waters chlorophyll-normalised carbon fixation was 2-3 times higher for nanoplankton and differences in picoplankton and nanoplankton carbon to chlorophyll-alpha ratios may lead to either higher or similar growth rates. These low chlorophyll-normalised carbon fixation rates for picoplankton may also reflect losses of fixed carbon (cell leakage or respiration), decreases in photosynthetic efficiency, grazing losses during the incubations, or some combination of all these. Comparison of nitrate concentrations in the subsurface chlorophyll maximum with estimates of those required to support the observed rates of carbon fixation (assuming Redfield stoichiometry) indicate that primary production in the chlorophyll maximum may be light rather than nutrient limited.
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3.
  • Forsman, Jan, et al. (författare)
  • Prewetting and layering in athermal polymer solutions
  • 2005
  • Ingår i: Physical Review Letters. - 1079-7114. ; 94:11, s. 1-118301
  • Tidskriftsartikel (refereegranskat)abstract
    • Coexistence conditions for prewetting and layering at a hard surface in additive hard sphere polymer solutions, where the solvent particles are smaller than the monomers, have been calculated by density functional methods. Various chain lengths and pressures have been investigated. An unexpected finding is that prewetting in these systems may proceed below the bulk critical pressure. We rationalize this behavior in terms of local properties of the pressure tensor. For longer chains, a different behavior is observed where the systems display a lower wetting pressure, i.e., a low pressure bound for surface wetting.
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4.
  • Woodward, C. E., et al. (författare)
  • Exact density functional theory for ideal polymer fluids with nearest neighbor bonding constraints
  • 2008
  • Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 129:5
  • Tidskriftsartikel (refereegranskat)abstract
    • We present a new density functional theory of ideal polymer fluids, assuming nearest-neighbor bonding constraints. The free energy functional is expressed in terms of end site densities of chain segments and thus has a simpler mathematical structure than previously used expressions using multipoint distributions. This work is based on a formalism proposed by Tripathi and Chapman [Phys. Rev. Lett. 94, 087801 (2005)]. Those authors obtain an approximate free energy functional for ideal polymers in terms of monomer site densities. Calculations on both repulsive and attractive surfaces show that their theory is reasonably accurate in some cases, but does differ significantly from the exact result for longer polymers with attractive surfaces. We suggest that segment end site densities, rather than monomer site densities, are the preferred choice of "site functions" for expressing the free energy functional of polymer fluids. We illustrate the application of our theory to derive an expression for the free energy of an ideal fluid of infinitely long polymers. (C) 2008 American Institute of Physics.
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