| 1. |
- Sun, S. G., et al.
(författare)
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Studies on a series of rhenium(I) bipyridyl photosensitive dyes
- 2004
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Ingår i: Youji huaxue. - 0253-2786. ; 24:8, s. 953-956
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Tidskriftsartikel (refereegranskat)abstract
- A series of rhemium(I) 2,2'-bipyridyl complexes [fac-(4,4'-di-COOEt-bpy)Re(CO)(3)(Xpy)PF6] (bpy = 2, 2'-bipyridine; py = pyridine; X = 3-methyl, 3-hydroxy, 3-amino, H) were synthesized. Their electrochemical properties, ground state electronic spectra and emission spectra were studied in acetonitrile. As the X group became more electron donating from H to 3-methyl, 3-hydroxy or 3-amino, the Re(II/I) oxidation potentials declined, the MLCT absorption maximum of the complex was changed little, the emission maximum blue-shifted, and the emission intensity and the fluorescence lifetime were decreased.
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| 2. |
- Chen, Xiangrong, 1982, et al.
(författare)
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Study on conducting characteristics of electrical trees in cross-linked polyethylene cable insulation
- 2012
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Ingår i: Wuli Xuebao/Acta Physica Sinica. - : Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences. - 1000-3290. ; 61:8, s. Art. no. 087701-
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Tidskriftsartikel (refereegranskat)abstract
- The conducting characteristics of two typical electrical trees in cross-linked polyethylene (XLPE) cable insulation are studied by a combination of optical microscopy observation, partial discharge measurement and con-focal Raman spectroscopy analysis. Although they are grown under similar conditions, these two trees display very different shapes. One is a typical branch-pine tree grown at 9 kV, and the other is a branch tree grown at 11 kV. The growth and the partial discharge regularities show obvious differences. The disordered graphitic carbon is condensed in the main tree channels of the branch-pine tree. From the relative intensity of the graphitic carbon G band to D band, the graphitic domain is estimated to be about 8 nm in size. The tree channel resistance per unit length is less than 10 Ω· μm-1, which is sufficient to prevent the partial discharge from developing within the tree structure. The branch-pine tree shows the features of the conducting tree. The fluorescence background is observed in the channels of branch tree, which shows the existence of the products of the material degradation, but no disordered graphitic carbon is observed in these tree channels. These tree channels display obvious non-conducting characteristics, which is not sufficient to prevent the continuous effect of the partial discharges. Finally, a single channel growth model is proposed for the conducting and non-conducting trees grown in XLPE cable insulation. Based on the equivalent circuit theory, the growth mechanisms of the two trees with different conducting characteristics in XLPE cable insulation are discussed.
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| 3. |
- Sun, S. G., et al.
(författare)
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Synthesis of rhenium(I) bipyridyl and ruthenium(II) tris-bipyridyl photosensitive dyes used for solar cells
- 2004
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Ingår i: Gaodeng xuéxiào huàxué xuébào. - 0251-0790. ; 25:1, s. 67-70
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Tidskriftsartikel (refereegranskat)abstract
- There has been a growing effort to convert solar energy into electricity in recent years. In order to get a stable solar cell system and acquire a high incident photon-to-current conversion efficiency(IPCE), two novel rhenium(I) bipyridyl and ruthenium(II) tris-bipyridyl photosensitive dyes were synthesized, the ethoxycarbonyl group in the dyes could be employed for covalently linking to the surface of the nanostructured TiO2. Their structures, photophysical and electrochemical properties were studied. The UV-Vis absorption maxima were 382 and 476 nm; emission maxima were 622 and 672 nm, respectively. The Re(I/II) oxidation potential is significantly positive than that of Ru(II/III) which provides a larger driving force for electron transfer. The results show that they both have proper redox potentials, enough stability and are suitable for being used as photosensitizers of solar cells.
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