| 1. |
- Abraham, T., et al.
(författare)
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Polyelectrolyte-mediated interaction between similarly charged surfaces : Role of divalent counter ions in tuning surface forces
- 2001
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Ingår i: Langmuir. - : American Chemical Society (ACS). - 0743-7463 .- 1520-5827. ; 17:26, s. 8321-8327
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Tidskriftsartikel (refereegranskat)abstract
- The effects of divalent salts (CaCl2, MgCl2 and BaCl2) in promoting the adsorption of weakly charged polyelectrolyte (polyacrylic acid), PAA, Mw similar to 250000 g/mol) on mica surfaces and their role in tuning the nature of interactions between such adsorbed polyelectrolyte layers were studied using the interferometric surface forces apparatus. With mica surfaces in 3 mM MgCl2 solutions at pH similar to8.0-9.0, the addition of 10 ppm PAA resulted in a long-range attractive bridging force and a short-range repulsive steric force. This force profile indicates a low surface coverage and weak adsorption. The range of the force can be related to the characteristic length scale R-G of polyelectrolyte chains using a scaling description. An increase of the PAA concentration to 50 ppm changed the attractive force profile to a monotonic, long-range repulsive interaction extending up to 600 Angstrom due to the increased surface coverage of polyelectrolyte chains on the mica surfaces. Comparison of the measured forces with a scaling mean field model suggests that the adsorbed polyelectrolyte chains are stretched, which eventually give rise to the polyelectrolyte brush like structure. When the mica surfaces were preincubated in 3 mM CaCl2 at pH similar to8.0-9.0, in contrast to the case of 3 MM MgCl2, the addition of 10 ppm PAA resulted in a more complex force profile: long-range repulsive forces extending up to 800 Angstrom followed by an attractive force regime and a second repulsive force regime at shorter separations. The long-range electrosteric forces can be attributed to strong adsorption of polyelectrolyte chains on mica surfaces (high surface coverage) which is facilitated by the presence of Ca2+ ions, while the intermediate range attractive forces can be ascribed to Ca2+ assisted bridging between adsorbed polyelectrolyte chains. Also interesting is to note various relaxation processes present in this system. In contrast to both MgCl2 and CaCl2 systems, with mica surfaces in 3 mM BaCl2 solution at pH similar to8.0-9.0, the addition of 10 ppm PAA resulted in precipitation of polyelectrolyte chains on mica surfaces, resulting in an extremely long-range monotonic repulsive force profile. In summary, our study showed that divalent counterions (Mg2+, Ca2+, and Ba2+) exhibit significantly different behavior in promoting PAA adsorption on mica surfaces, modifying and controlling various surface interactions.
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| 2. |
- Zhang, L., et al.
(författare)
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Quantum Noise Secured Terahertz Communications
- 2023
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Ingår i: IEEE Journal of Selected Topics in Quantum Electronics. - : Institute of Electrical and Electronics Engineers Inc.. - 1077-260X .- 1558-4542. ; 29:5
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Tidskriftsartikel (refereegranskat)abstract
- The terahertz communications display an important role in high-speed wireless communications, the security threat from the eavesdroppers in the terahertz communications has been gaining attention recently. The true randomness in the physical layer can ensure one-time-pad encryption for secured terahertz communications, however, physical layer security schemes like the quantum key distribution methods suffer from device imperfections that limit the desirable signal rate and link distance. Herein, we present the quantum noise secured terahertz wireless communications with photonic terahertz signal generation schemes. With the high-order diffusion algorithms, the signal is masked by the quantum noise ciphers to the eavesdroppers and cannot be detected because the inevitable randomness by quantum noise measurement will cause physical measurement errors. In the experiment, we demonstrate 16 Gbits-1 quantum noise secured terahertz wireless communications with the conventional optical communication realms and devices, operating at 300 GHz terahertz frequency. This quantum noise secured terahertz communication approach is a significant step toward high-security wireless communications.
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| 3. |
- Zhou, R., et al.
(författare)
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Maritime Disruption Impact Evaluation Using Simulation and Big Data Analytics
- 2022
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Ingår i: Proceedings - Winter Simulation Conference. - : Institute of Electrical and Electronics Engineers Inc.. - 9798350309713 ; , s. 784-795
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Konferensbidrag (refereegranskat)abstract
- Disruptions in maritime networks may cause significant financial burden and damage to business. Recently, some international ports have been experiencing unprecedented congestions due to the COVID19 pandemic and other disruptions. It is paramount for the maritime industry to further enhance the capability to assess and predict impacts of disruptions. With more data available from industrial digitization and more advanced technologies developed for big data analytics and simulation, it is possible to build up such capability. In this study, we developed a discrete event simulation model backed with big data analytics for realistic and valid inputs to assess impacts of the Suez Canal blockage to the Port of Singapore. The simulation results reveal an interesting finding that, the blockage occurred in the Suez Canal can hardly cause significant congestion in the Port of Singapore. The work can be extended to evaluate impacts of other types of disruptions, even occurring concurrently.
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