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- 2019
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Tidskriftsartikel (refereegranskat)
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| 3. |
- Fang, Shuhong, et al.
(författare)
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Environment occurrence of perfluoroalkyl acids and associated human health risks near a major fluorochemical manufacturing park in southwest of China
- 2020
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Ingår i: Journal of Hazardous Materials. - : Elsevier BV. - 0304-3894 .- 1873-3336. ; 396
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Tidskriftsartikel (refereegranskat)abstract
- Despite China being the largest global manufacturer of perfluoroalkyl acids (PFAAs), few studies have been carried out on the environmental occurrence and associated human health risks of PFAAs emitted from manufacturing sites in China. Here, river water, tap water, soil and leaf samples were collected around a major fluorochemical manufacturing park (FMP) in the southwest of China in 2019. High EPFAA concentrations (sum of 12 PFAAs) of 3817 ng/L, 3254 ng/L, 322 - 476 ng/g dw and 23401-33749 ng/g dw were measured near the FMP in river water, tap water, soil and leaves, respectively, indicating that the FMP is a point source of PFAAs. PFOA was the predominant PFAA in all samples (58.5-98.6 %) indicating the production or use of PFOA at the FMP. PFOA concentrations in most tap water samples (> 300 ng/L in 31 of 38 samples) exceeded the U.S. EPA health advisory. Proportions of branched PFOA isomers in all samples were in 5.9-47.4 %, suggesting the production or use of PFOA manufactured by electrochemical fluorination at the FMP. It is recommended to focus more attention on branched PFOA isomers in the future because otherwise health risks may be underestimated due to their relatively high proportions in China.
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| 4. |
- Castro, Mafalda, et al.
(författare)
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Bioaccumulation Potential of CPs in Aquatic Organisms : Uptake and Depuration in Daphnia magna
- 2019
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Ingår i: Environmental Science and Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 53:16, s. 9533-9541
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Tidskriftsartikel (refereegranskat)abstract
- Chlorinated paraffins (CPs) are industrial chemicals, subdivided into three categories: short chain (SCCPs), medium chain (MCCPs), and long chain (LCCPs) chlorinated paraffins. SCCPs are currently restricted in Europe and North America. MC and LCCPs are being used as substitution products, but there is a knowledge gap concerning their bioaccumulation potential in aquatic organisms. In this work, we performed laboratory bioconcentration (passive uptake) and bioaccumulation (including dietary uptake) experiments with Daphnia magna using five different CP technical substances. All tested CP technical substances were bioaccumulative in D. magna, with log BCF and log BAF values ranging between 6.7-7.0 and 6.5-7.0 (L kg lipid(-1)), respectively. An increase in carbon chain length and an increase in chlorine content (% w/w) of the CP technical substances had significant positive effects on the log BCF and log BAF values. For the different CP technical substances, 50% depuration was achieved after 2 to 10 h when D. magna were transferred to clean media. Our results show that SC, MC, and LCCPs are (very)bioaccumulative in aquatic organisms. We believe these data can aid the ongoing policy discussion concerning the environmental risk posed by CPs.
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- Castro, Mafalda, et al.
(författare)
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Partitioning of Chlorinated Paraffins (CPs) to Daphnia magna Overlaps between Restricted and in-Use Categories
- 2018
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Ingår i: Environmental Science and Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 52:17, s. 9713-9721
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Tidskriftsartikel (refereegranskat)abstract
- Chlorinated paraffins (CPs) are high-production volume industrial chemicals consisting of n-alkanes (with 10 to 30 carbon atoms in the chain) with chlorine content from 30 to 70% of weight. In Europe, the use of short chain chlorinated paraffins (SCCPs) has been restricted by the Stockholm Convention on POPs due to their PBT (persistent, bioaccumulative and toxic) properties. Medium (MCCPs) and long chain (LCCPs) chlorinated paraffins are used as substitution products. In this work we studied the partitioning behavior of five different CP technical mixtures from the established categories (2 SCCPs, 1 MCCP, 1 LCCP and 1 CP technical mixture covering all categories) using passive dosing, by determining the partitioning coefficient of CP technical mixtures between silicone and water (Ksilicone-water) as well as between organic matter and water (Koc-water). We show that both silicone-water and organic carbon water partition coefficients overlap between different categories of CP technical mixtures. These results indicate that in-use MCCPs and LCCPs may be equally or more bioaccumulative than restricted SCCPs. For the tested mixtures, both chlorine content and carbon chain length showed a significant correlation with both Ksilicone-water and Koc-water.
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- Chang, Jian, 1990-, et al.
(författare)
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MXene/Cellulose Composite Cloth for Integrated Functions (if-Cloth) in Personal Heating and Steam Generation
- 2024
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Ingår i: Advanced fiber materials. - 2524-7921. ; 6:1, s. 252-263
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Tidskriftsartikel (refereegranskat)abstract
- Given the abundant solar light available on our planet, it is promising to develop an advanced fabric capable of simultaneously providing personal thermal management and facilitating clean water production in an energy-efficient manner. In this study, we present the fabrication of a photothermally active, biodegradable composite cloth composed of titanium carbide MXene and cellulose, achieved through an electrospinning method. This composite cloth exhibits favorable attributes, including chemical stability, mechanical performance, structural flexibility, and wettability. Notably, our 0.1-mm-thick composite cloth (RC/MXene IV) raises the temperature of simulated skin by 5.6 degrees C when compared to a commercially available cotton cloth, which is five times thicker under identical ambient conditions. Remarkably, the composite cloth (RC/MXene V) demonstrates heightened solar light capture efficiency (87.7%) when in a wet state instead of a dry state. Consequently, this cloth functions exceptionally well as a high-performance steam generator, boasting a superior water evaporation rate of 1.34 kg m(-2) h(-1) under one-sun irradiation (equivalent to 1000 W m(-2)). Moreover, it maintains its performance excellence in solar desalination processes. The multifunctionality of these cloths opens doors to a diverse array of outdoor applications, including solar-driven water evaporation and personal heating, thereby enriching the scope of integrated functionalities for textiles.
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| 9. |
- Chibwe, Leah, et al.
(författare)
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C12-30 alpha-Bromo-Chloro Alkenes : Characterization of a Poorly Identified Flame Retardant and Potential Environmental Implications
- 2019
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Ingår i: Environmental Science and Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 53:18, s. 10835-10844
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Tidskriftsartikel (refereegranskat)abstract
- Bromo-chloro alkenes (Br-Cl PXAs) have been used for over 30 years as flame retardants and are listed on several national chemical inventories. Very little publicly available information is available on Br-Cl PXAs, and thus preliminary ecological risk screening is challenging due to the lack of basic information such as molecular structure and associated physicochemical properties. Due to their likely similarity with chlorinated paraffins (CPs), Br-Cl PXAs may pose a similar environmental hazard. Several structural databases list such substances as alkenes, although the industrial synthesis involves halogenation of linear alpha-olefins and would be expected to produce linear alkanes. In this study, a combination of high-resolution separation and mass spectrometric techniques were used to characterize a Br-Cl PXA industrial technical product, C12-30 bromo-chloro alpha-alkenes (CAS RN 68527-01-5). The results show this product is dominated by C-18 carbon chain lengths, substituted with 3-7 chlorine atoms and 1-3 bromine atoms on an alkane chain. Long-chain C-18 chlorinated paraffins are also present, although they represent a relatively minor component. Experimental log K-OW (6.9 to 8.6) and estimated log K-OA (10.5 to 13.5) and log K-AW (-5.1 to -0.6) partition coefficients suggest that this chemical will behave similarly to medium- and long-chain CPs as well as other persistent organic pollutants, such as highly chlorinated pesticides and polychlorinated biphenyls. The results of this study provide an initial step toward understanding the environmental behavior and persistence of Br-Cl PXAs, highlighting the need for further assessment and re-evaluation of the current structure(s) assigned to these compounds.
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| 10. |
- de Wit, Cynthia A., et al.
(författare)
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Organohalogen compounds of emerging concern in Baltic Sea biota : Levels, biomagnification potential and comparisons with legacy contaminants
- 2020
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Ingår i: Environment International. - : Elsevier BV. - 0160-4120 .- 1873-6750. ; 144
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Tidskriftsartikel (refereegranskat)abstract
- While new chemicals have replaced major toxic legacy contaminants such as polychlorinated biphenyls (PCBs) and dichlorodiphenyltrichloroethane (DDT), knowledge of their current levels and biomagnification potential in Baltic Sea biota is lacking. Therefore, a suite of chemicals of emerging concern, including organophosphate esters (OPEs), short-chain, medium-chain and long-chain chlorinated paraffins (SCCPs, MCCPs, LCCPs), halogenated flame retardants (HFRs), and per- and polyfluoroalkyl substances (PFAS), were analysed in blue mussel (Mytilus edulis), viviparous eelpout (Zoarces viviparus), Atlantic herring (Clupea harengus), grey seal (Halichoerus grypus), harbor seal (Phoca vitulina), harbor porpoise (Phocoena phocoena), common eider (Somateria mollissima), common guillemot (Uria aalge) and white-tailed eagle (Haliaeetus albicilla) from the Baltic Proper, sampled between 2006 and 2016. Results were benchmarked with existing data for legacy contaminants. The mean concentrations for Sigma OPEs ranged from 57 to 550 ng g(-1) lipid weight (lw), for Sigma CPs from 110 to 640 ng g(-1) lw for Sigma HFRs from 0.42 to 80 ng g(-1) lw, and for Sigma PFAS from 1.1 to 450 ng g(-1) wet weight. Perfluoro-4-ethyl-cyclohexanesulfonate (PFECHS) was detected in most species. Levels of OPEs, CPs and HFRs were generally similar or higher than those of polybrominated diphenyl ethers (PBDEs) and/or hexabromocyclododecane (HBCDD). OPE, CP and HFR concentrations were also similar to PCBs and DDTs in blue mussel, viviparous eelpout and Atlantic herring. In marine mammals and birds, PCB and DDT concentrations remained orders of magnitude higher than those of OPEs, CPs, HFRs and PFAS. Predator-prey ratios for individual OPEs (0.28-3.9) and CPs (0.40-5.0) were similar or somewhat lower than those seen for BDE-47 (5.0-29) and HBCDD (2.4-13). Ratios for individual HFRs (0.010-37) and PFAS (0.15-47) were, however, of the same order of magnitude as seen for p,p'-DDE (4.7-66) and CB-153 (31-190), indicating biomagnification potential for many of the emerging contaminants. Lack of toxicity data, including for complex mixtures, makes it difficult to assess the risks emerging contaminants pose. Their occurence and biomagnification potential should trigger risk management measures, particularly for MCCPs, HFRs and PFAS.
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