| 1. |
- Zhao, K., et al.
(author)
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Studies on two-photon absorption cross-sections of 1,4-dimethoxy-2,5-divinyl-benzene derivatives
- 2005
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In: Wuli xuebao. - : Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences. - 1000-3290. ; 54:6, s. 2662-2668
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Journal article (peer-reviewed)abstract
- The one-photon and two-photon absorption properties of a series of 1, 4-dimethoxy-2, 5-divinyl-benzene derivatives are investigated by use of the analytic response theory at HF level. The one-photon and two-photon fluorescence spectra of E, E-2-5Bis[4'-(N, N-di-n-butylamino) styryl]-1 4-dimenthoxybenzene are measured. The numerical results show that these molecules have strong two-photon absorption cross sections. In the visible light region, the maximal one-photon absorption strengths of the molecules occur in the first excited state. Furthermore, the maximal two-photon absorption cross sections of the D-pi-A typed molecules still appear in the first state, but for D-pi-D typed molecules the second excited state has the maximal two-photon absorption cross-section. The optical properties of the molecules are closely related to the electric property of the donor and acceptor. The symmetrically substituted molecules can not be determined to have a larger two-photon absorption cross section than the asymmetrically substituted molecules for such a kind of pi-center. The charge-transfer process for the charge-transfer states is displayed, and then the mechanism of photopolymerization is discussed qualitatively.
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| 2. |
- Fu, L. H., et al.
(author)
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Influence of Cr3C2 content on the wear properties of Cr3C2/Ni3Al composites
- 2016
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In: Gongcheng Kexue Xuebao/Chinese Journal of Engineering. - 2095-9389. ; 38:8, s. 1145-1152
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Journal article (peer-reviewed)abstract
- The Ni3Al-alloy and its composites with different Cr3C2 contents were fabricated by a hot isostatic pressing (HIP) technique. The influences of Cr3C2 content on the microstructure, hardness and wear properties of the Cr3C2/Ni3Al composites were investigated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and wear tribometry. The results show that inter-diffusion occurs between the original Cr3C2 and the Ni3Al particles during the HIP process and the Cr3C2 particles partially transform into M7C3 (M=Cr, Fe, Ni) structures. Under specific friction and wear conditions, the wear resistance of the Cr3C2/Ni3Al composites is significantly improved due to the addition of Cr3C2 particles by about 4-10 times, compared to the Ni3Al alloy. In addition, the cutting and scraping effects of counter-part disks by the Cr3C2/Ni3Al composites decreases with increasing Cr3C2 addition, resulting in a reduction in wear rate of counter-part disks.
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| 3. |
- Fu, L. H., et al.
(author)
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Microstructure and phases constitution of Cr3C2/Ni3Al composites prepared by hot isostatic pressing (HIP)
- 2016
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In: Journal of Iron and Steel Research. - 1001-0963. ; 28:12, s. 52-58
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Journal article (peer-reviewed)abstract
- The Cr3Cj/Ni3Al composite materials were prepared by hot isostatic pressing (HIP) at 1160°C and 100MPa. Microstructure and phases constitution of the composite materials were investigated. The results indicate that the original Cr3C2 particle firstly dissolves into Cr and C atoms and then diffuses into the matrix. During the cooling process, the dissolved Cr and C atoms transformed into a stable Cr7C3 structure. Also, an uphill diffusion phenomenon is observed for Fe element from the matrix to the Cr7C3 carbide phase, which is attributed to the easy formation of stable carbides of Fe element in Ni3Al alloy with C element. And, the Fe atoms substitute a part of Cr atoms in Cr7C3 carbides and form a diffusion phase with M7 C3 (M for Cr, Fe) structure. When the original Cr3Q2 particles are large, it cannot be completely dissolved during the high temperature period. The undissolved core of Cr3C2 particles still remain the Cr3C2 structure after the cooling process. The Cr3C2/Ni3 Al composite materials are composed of Cr3C2 hard core phase, M7C3 diffusion phase and ?-Ni3Al matrix material phase. The Cr3C2 hard core phase and the ?'-Ni3Al matrix created a good diffusion bonding by the formed M7C3 diffusion phase. Therefore, the Cr3C2 particle on the worn surface does not peel off and the groove is interrupted around the chromium carbides during the wear test, resulting in significantly improved wear resistance of Cr3C2/Ni3Al composites.
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