| 1. |
- Fu, Yifeng, 1984, et al.
(författare)
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Selective growth of double-walled carbon nanotubes on gold films
- 2012
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Ingår i: Materials Letters. - : Elsevier BV. - 1873-4979 .- 0167-577X. ; 72, s. 78-80
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Tidskriftsartikel (refereegranskat)abstract
- Growth of high-quality vertical aligned carbon nanotube (CNT) structures on silicon supported gold (Au) films by thermal chemical vapor deposition (TCVD) is presented. Transmission electron microscopy (TEM) images show that the growth is highly selective. Statistical study reveals that 79.4% of the as-grown CNTs are double-walled. The CNTs synthesized on Au films are more porous than that synthesized on silicon substrates under the same conditions. Raman spectroscopy and electrical characterization performed on the as-grown double-walled CNTs (DWNTs) indicate that they are competitive with those CNTs grown on silicon substrates. Field emission tests show that closed-ended DWNTs have lower threshold field than those open-ended.
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| 2. |
- Fu, Yifeng, 1984, et al.
(författare)
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Templated Growth of Covalently Bonded Three-Dimensional Carbon Nanotube Networks Originated from Graphene
- 2012
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Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 24:12, s. 1576-1581
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Tidskriftsartikel (refereegranskat)abstract
- A template-assisted method that enables the growth of covalently bonded three-dimensional carbon nanotubes (CNTs) originating from graphene at a large scale is demonstrated. Atomic force microscopy-based mechanical tests show that the covalently bonded CNT structure can effectively distribute external loading throughout the network to improve the mechanical strength of the material.
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| 3. |
- Sun, Jie, 1977, et al.
(författare)
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Direct Chemical Vapor Deposition of Large-Area Carbon Thin Films on Gallium Nitride for Transparent Electrodes: A First Attempt
- 2012
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Ingår i: IEEE Transactions on Semiconductor Manufacturing. - : Institute of Electrical and Electronics Engineers (IEEE). - 0894-6507 .- 1558-2345. ; 25:3, s. 494-501
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Tidskriftsartikel (refereegranskat)abstract
- Direct formation of large-area carbon thin films on gallium nitride by chemical vapor deposition without metallic catalysts is demonstrated. A high flow of ammonia is used to stabilize the surface of the GaN (0001)/sapphire substrate during the deposition at 950 degrees C. Various characterization methods verify that the synthesized thin films are largely sp(2) bonded, macroscopically uniform, and electrically conducting. The carbon thin films possess optical transparencies comparable to that of exfoliated graphene. This paper offers a viable route toward the use of carbon-based materials for future transparent electrodes in III-nitride optoelectronics, such as GaN-based light emitting diodes and laser diodes.
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| 4. |
- Zhang, Zhfei, et al.
(författare)
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Characterization of CNT Enhanced Conductive Adhesives in Terms of Thermal Conductivity
- 2012
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Ingår i: ECS Transactions. - : The Electrochemical Society. - 1938-5862 .- 1938-6737. - 9781607683186 ; 44:1, s. 1011-1017
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Konferensbidrag (refereegranskat)abstract
- CNTs have excellent thermal, electrical and mechanical properties. They can be used in various ways. One researched field of application is CNT-polymer composites which combine common technologies with advanced materials. This paper will focus on the thermal property of CNT-Ag-filled adhesives and compares the new materials with conventional, electrical Ag-filled conductive adhesives. Several analytical methods, FTIR, Raman analysis, SEM and TEM have been carried out to examine the different surface conditions after physicval and chemical modification of CNTs. The thermal conductivities of composites containing different types of CNTs were investigated. The incorporation of CNTs into polymers resulted in enhancement of the thermal conductivity compared to Ag-filler. The increase of thermal conductivity with addition of CNT filler is obvious, especially for the purified CNT. The value of thermal conductivity is about two times higher than the Ag-filled conductive adhesive. However, improvement on thermal conductivity of the surface modified CNT-filled conductive adhesives is not so obvious. Since the thermal conduction in CNT is by phonon transfer, the nanometric size and the huge interface lead to strong phonon-scattering at the interface. Thus, a relatively low interfacial area, weak interfacial adhesion promotes the conduction of phonons and minimizes coupling losses. According to this, the non-treated MWCNTs seem to have the highest potential to improve the thermal conductivity of epoxies.
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| 5. |
- Carlberg, Björn, 1983, et al.
(författare)
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Polymer-metal nanofibrous composite for thermal management of microsystems
- 2012
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Ingår i: Materials Letters. - : Elsevier BV. - 1873-4979 .- 0167-577X. ; 75, s. 229-232
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Tidskriftsartikel (refereegranskat)abstract
- In this letter, a composite structure based on a porous electrospun polyimide structure infiltrated with indium aimed at thermal interface material applications is presented. A porous nanofibrous structure was prepared by electrospinning of polyimide. An interfacial nanocomposite layer of silver nanoparticles partially or fully embedded in the polyimide matrix was synthesized on the fiber surfaces, followed by autocatalytic deposition of a uniform silver coating (using the interfacial layer as an anchored seed layer) serving as a reactive wetting layer for the infiltrating melt. The thermal performance of the composite was evaluated and the thermal conductivity was determined to be 27 W/mK, accompanied by low contact resistance of the metallurgical bond (
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| 6. |
- Duan, Y., et al.
(författare)
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A New Thermally Conductive Thermoplastic Die Attach Film
- 2012
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Ingår i: Proceedings of IEEE CPMT 2012 International Conference on Electronic Packaging Technology & High Density Packaging. - 9781467316804 ; , s. 212-215
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Konferensbidrag (refereegranskat)abstract
- As devices with smaller footprint and, higher functionality become the norm, stacked die technology will be required to enable the advancement of modern integrated packaging. As wafers become ever thinner to meet stacking requirements, new materials technology must address the challenges of handling and processing wafer thicknesses of less than 100 microns. Die attach film (DAF) has being widely used as an alternative. With its good control of bleed, consistent bond line thickness and simplified operation. In this paper, a kind of thermoplastic film with good thermal conductivity was developed for die attachment application and some of its properties, such as shear strength and, thermal conductivity were investigated. In the present work, the formula of the DAF matrix has been determined and in order to improve thermal conductivity of DAF, silicon carbide (SiC) particles with high thermal conductivity were selected to add as filler and in the content of SiC particles on the property of the DAFs were also investigated. Shear tests were conducted to measure the bonding strength of the DAFs. The results show that the films reached a 6.5 MPa in terms of average shear strength and after plasticizing it could reach 3.5 MPa. The thermal conductivity of the DAFs was 0.37W/ m·K.
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| 7. |
- Fu, Yifeng, 1984, et al.
(författare)
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A complete carbon-nanotube-based on-chip cooling solution with very high heat dissipation capacity
- 2012
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Ingår i: Nanotechnology. - : IOP Publishing. - 1361-6528 .- 0957-4484. ; 23:4
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Tidskriftsartikel (refereegranskat)abstract
- Heat dissipation is one of the factors limiting the continuous miniaturization of electronics. In the study presented in this paper, we designed an ultra-thin heat sink using carbon nanotubes (CNTs) as micro cooling fins attached directly onto a chip. A metal-enhanced CNT transfer technique was utilized to improve the interface between the CNTs and the chip surface by minimizing the thermal contact resistance and promoting the mechanical strength of the microfins. In order to optimize the geometrical design of the CNT microfin structure, multi-scale modeling was performed. A molecular dynamics simulation (MDS) was carried out to investigate the interaction between water and CNTs at the nanoscale and a finite element method (FEM) modeling was executed to analyze the fluid field and temperature distribution at the macroscale. Experimental results show that water is much more efficient than air as a cooling medium due to its three orders-of-magnitude higher heat capacity. For a hotspot with a high power density of 5000 W cm(-2), the CNT microfins can cool down its temperature by more than 40 degrees C. The large heat dissipation capacity could make this cooling solution meet the thermal management requirement of the hottest electronic systems up to date.
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| 8. |
- Fu, Yifeng, 1984, et al.
(författare)
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Thick film patterning by lift-off process using double-coated single photoresists
- 2012
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Ingår i: Materials Letters. - : Elsevier BV. - 1873-4979 .- 0167-577X. ; 76, s. 117-119
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Tidskriftsartikel (refereegranskat)abstract
- A novel method using lift-off process for patterning very thick materials is developed and demonstrated. Unlike conventional lift-off processes, no special lift-off resist is used in this method. Instead, only a double-coated single photoresist is needed. Demonstrations using two commercial photoresists show that good patterning morphology and obvious undercuts as high as 15 mu m are obtained for lift-off, which is very difficult to achieve by existing methods. The application and feasibility of this approach is demonstrated by a carbon nanotube transfer process. This simple and effective method offers wider option to pattern very thick materials in high quality which are in strong demands.
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| 9. |
- Gao, Zhaoli, et al.
(författare)
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Graphene Heat Spreader for Thermal Management of Hot Spots in Electronic Packaging
- 2012
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Ingår i: Proceedings of the 18th Therminic International Workshop on Thermal Investigations of ICs and Systems. - 9782355000225 ; , s. 217-220
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Konferensbidrag (refereegranskat)abstract
- Monolayer graphene was fabricated using thermal CVD for the application of heat spreader in electronic packaging. Platinum (Pt) micro-heater embedded thermal testing chips were utilized to evaluate the thermal performance of the graphene heat spreader. The hot spot temperature was decreased by about 5 degrees C at a heat flux of up to 800W/cm2. It is possible to further improve the thermal performance of graphene heat spreader by optimizing the synthesis parameters and transfer process.
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| 10. |
- Hu, Zhili, 1983, et al.
(författare)
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Detecting single molecules inside a carbon nanotube to control molecular sequences using inertia trapping phenomenon
- 2012
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 101:13, s. Art. no. 133105-
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Tidskriftsartikel (refereegranskat)abstract
- Here we show the detection of single gas molecules inside a carbon nanotube based on the change inresonance frequency and amplitude associated with the inertia trapping phenomenon. As its directimplication, a method for controlling the sequence of small molecule is then proposed to realize theconcept of manoeuvring of matter atom by atom in one dimension. The detection as well as theimplication is demonstrated numerically with the molecular dynamics method. It is theoreticallyassessed that it is possible for a physical model to be fabricated in the very near future.
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