| 11. |
- Chen, Jiajia, et al.
(författare)
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Characterization of Longitudinal Thermal Conductivity of Graphene Film
- 2021
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Ingår i: 2021 22nd International Conference on Electronic Packaging Technology, ICEPT 2021.
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Konferensbidrag (refereegranskat)abstract
- The chase of high performance by chip manufacturers has greatly increased the power consumption of integrated circuits, which brings great challenges to the heat dissipation of electronics systems. It has also slowed down following up of the Moore's Law, and it is expected to hit the wall soon [1]. Graphene film with high in-plane thermal conductivity is one of the key materials to make it possible for electronics industry to continue to follow the Moore's Law. However, there are few studies focusing on the longitudinal thermal conductivity of graphene films. The purpose of this study is to investigate the longitudinal thermal conductivity of graphene films according to ASTM D5470 [2]. The results show that the longitudinal thermal conductivity of the pressed graphene film is greater than that of the unpressurized graphene film. The longitudinal thermal conductivity is 10.6 W/m· K for the unpressurized graphene film and 20.6 W/m· K for the pressed graphene film.
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| 12. |
- Chen, Shujing, et al.
(författare)
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Scalable production of thick graphene films for next generation thermal management applications
- 2020
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Ingår i: Carbon. - : Elsevier BV. - 0008-6223. ; 167, s. 270-277
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Tidskriftsartikel (refereegranskat)abstract
- With the increasing demand on integration and better performance of portable electronics devices, the system operation temperatures are expected to continue to increase, leading eventually to degeneration in functional performance and reliability. Therefore, demand for thermal management materials that effectively spread heat and reduce heat density is urgent. The existing solution of pyrolytic graphite film (PGF) is unsatisfactory due to their low heat flux carrying capacity or low thermal conductivity, as well as poor mechanical performance. This work solves the problem by substituting ultra-thick (>75 mm) graphene film (GF) for PGF, offering more than three times higher heat flux carrying capacity. The conjugation of large crystallinity and firm structures endows GFs with excellent thermal conductive performance (up to 1204 +/- 35 W m(-1) K-1), great heat flux carrying capacity, and good foldability (5000 cycles folding). In addition to this, such a GF is produced based on an economically efficient and quasi industrial method incorporating continuous high-pressure homogenization processing (HPH), indicating an enormous potential as a new pathway to thermal management applications.
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| 13. |
- Cui, Luqing, et al.
(författare)
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Low Cycle Fatigue Behavior and Microstructural Evolution of Nickel-based Superalloy M951G at Elevated Temperatures
- 2020
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Ingår i: Materials Characterization. - : Elsevier. - 1044-5803 .- 1873-4189. ; 163
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Tidskriftsartikel (refereegranskat)abstract
- Low cycle fatigue (LCF) tests of the newly developed nickel-based superalloy M951G have been conducted at 900 and 1000 °C under different total strain amplitudes. Results show that the fatigue properties, fracture mechanisms as well as coarsening of γ′ precipitates are dependent on testing temperatures and strain amplitudes. Fatigue life and cyclic stress response under the same total strain amplitude at 1000 °C are lower than that at 900 °C, which is due to the degradation of microstructures, shearing of γ′ precipitates by dislocations and serious oxidation. Fracture modes change from intergranular cracking to the mixed mode cracking as the strain amplitude increases. At low strain amplitudes, M951G alloy fails in the form of intergranular cracking owing to the oxidation of surface carbides and the relatively low deformation rate. At higher strain amplitudes, the strain localization in grain interior, the distribution of broken carbides and eutectics as well as the relatively higher strain rate are the main reasons for the formation of transgranular microcracks. Ultimately, the effects of fatigue conditions on coarsening of cubic γ′ precipitates are also analyzed from the aspect of γ′ volume fraction, fatigue life and flow stress difference between the γ/γ′ interfaces.
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| 14. |
- Enmark, Markus, 1991, et al.
(författare)
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A Critical Assessment of Nano Enhanced Vapor Chamber Wick Structures for Electronics Cooling
- 2021
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Ingår i: 2021 23rd European Microelectronics and Packaging Conference and Exhibition, EMPC 2021.
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Konferensbidrag (refereegranskat)abstract
- The increasing need for high thermal dissipation in small electronic products puts tough requirements on effective cooling solutions. Two of the most effective passive cooling devices in electronics today are vapor chambers and heat pipes. With new advancements in materials science and nanotechnology comes the possibility to further increase cooling capacity and at the same time make devices lighter. This study is a critical assessment on recent progress in the field of nanomaterial enhanced wick structures in vapor chambers and heat pipes. In this paper, nano-enhanced wick structures are divided into five different sub-categories based on material type. Publication trends for the different types of nano-enhanced wicks are studied by plotting them on a timeline. It is found that nanostructured metal wicks is the most studied field in recent years. A plot showing wick performance in terms of superheat temperatures for given heat flux is created to be used for benchmarking of new wick structures when pool boil experiments are carried out. An attempt to find correlation between publication trends, type of wick and performance is done. On the basis of the gathered data it is deemed difficult to find a distinct correlation, this is mainly due to difficulty in comparing performance between different studies, especially when different heat fluxes are used. There is no unambiguous answer to which category of nano-enhanced wicks that should be target for future studies. Graphene coating and pure carbon nanomaterials such as aerogels and graphene foam are still relatively unexplored and believed to have great potential if they can be attached to envelope materials.
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| 15. |
- Fazi, Andrea, 1992, et al.
(författare)
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Multiple growth of graphene from a pre-dissolved carbon source
- 2020
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Ingår i: Nanotechnology. - : IOP Publishing. - 1361-6528 .- 0957-4484. ; 31:34, s. 345601-
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Tidskriftsartikel (refereegranskat)abstract
- Mono- to few-layer graphene materials are successfully synthesized multiple times using Cu-Ni alloy as a catalyst after a single-chemical vapor deposition (CVD) process. The multiple synthesis is realized by extracting carbon source pre-dissolved in the catalyst substrate. Firstly, graphene is grown by the CVD method on Cu-Ni catalyst substrates. Secondly, the same Cu-Nicatalyst foils are annealed, in absence of any external carbon precursor, to grow graphene using the carbon atoms pre-dissolved in the catalyst during the CVD process. This annealing process is repeated to synthesize graphene successfully until carbon is exhausted in the Cu-Ni foils. After the CVD growth and each annealing growth process, the as-grown graphene is removed using a bubbling transfer method. A wide range of characterizations are performed to examine the quality of the obtained graphene material and to monitor the carbon concentration in the catalyst substrates. Results show that graphene from each annealing growth process possesses a similar quality, which confirmed the good reproducibility of the method. This technique brings great freedom to graphene growth and applications, and it could be also used for other 2D material synthesis.
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| 16. |
- Gong, Xinjian, et al.
(författare)
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Fabrication and Characterization of Graphene/polyimide Composite Film
- 2021
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Ingår i: 2021 23rd European Microelectronics and Packaging Conference and Exhibition, EMPC 2021.
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Konferensbidrag (refereegranskat)abstract
- A flexible graphene and polyimide composite film was designed and fabricated in this study. A polyimide solution was used as an adhesive layer to connect graphene film and polyimide film by hot-pressing. Laser flash thermal analysis method was carried out to evaluate the thermal diffusion coefficient of different thicknesses of the fabricated films at various temperatures. Bending test was carried out to evaluate the stability and reliability of the composite film. Scanning electron microscopy was applied to characterize the cross-section of the composite film before and after the peel test. IR imaging was employed to compare the heat diffusion of the composite film and traditional flexible copper clad laminate. The results show that the composite film has significantly better thermal diffusion capacity than traditional flexible copper clad laminate.
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| 17. |
- Guo, Sihua, et al.
(författare)
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Graphene-based films: Fabrication, interfacial modification, and applications
- 2021
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Ingår i: Nanomaterials. - : MDPI AG. - 2079-4991. ; 11:10
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Forskningsöversikt (refereegranskat)abstract
- Graphene-based film attracts tremendous interest in many potential applications due to its excellent thermal, electrical, and mechanical properties. This review focused on a critical analysis of fabrication, processing methodology, the interfacial modification approach, and the applications of this novel and new class material. Strong attention was paid to the preparation strategy and interfacial modification approach to improve its mechanical and thermal properties. The overview also discussed the challenges and opportunities regarding its industrial production and the current status of the commercialization. This review showed that blade coating technology is an effective method for industrial mass-produced graphene film with controllable thickness. The synergistic effect of different interface interactions can effectively improve the mechanical properties of graphenebased film. At present, the application of graphene-based film on mobile phones has become an interesting example of the use of graphene. Looking for more application cases is of great significance for the development of graphene-based technology.
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| 18. |
- Guo, Sihua, et al.
(författare)
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Synergistic Toughening of Graphene Films by Addition of Hydroxylated Carbon Nanotube
- 2021
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Ingår i: 2021 23rd European Microelectronics and Packaging Conference and Exhibition, EMPC 2021.
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Konferensbidrag (refereegranskat)abstract
- Graphene attracts great attention due to its excellent properties. However, the mechanical of assembled graphene-based film is usually inferior than its inherent mechanical properties. Herein, we construct a high-performance graphene-based film via vacuum filtration process by using graphene as matrix and hydroxylated Carbon Nanotube (CNT) as reinforcement agent. The synergistic interaction of hydrogen bonds between CNT and graphene Oxide (GO) and ionic bonds between Fe2+ on CNT and GO significantly improve the mechanical properties of free-standing and flexible rGO/CNT film. Scanning Electron Microscopic (SEM) imaging and stress transfer mechanism analysis show that the introduction of CNT can hinder the slippage of GO sheets and promote the stress transfer under the continuous loading. The obtained rGO/CNT film shows high toughness of 3 MJ/m3, which is 3.6 times higher than that of GO sheets. This facile and scalable strategy can pave the way for the fabrication of high-performance graphene-based film in various applications.
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| 19. |
- Hansson, Josef, 1991, et al.
(författare)
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Bipolar electrochemical capacitors using double-sided carbon nanotubes on graphite electrodes
- 2020
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Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753. ; 451
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Tidskriftsartikel (refereegranskat)abstract
- The electrochemical capacitor (EC) is a key enabler for the miniaturized self-powered systems expected to become ubiquitous with the advent of the internet-of-things (IoT). Vertically aligned carbon nanotubes (VACNTs) on graphite holds promise as electrodes for compact and low-loss ECs. However, as with all ECs, the operating voltage is low, and miniaturization of higher voltage devices necessitates a bipolar design. In this paper, we demonstrate a bipolar EC using graphite/VACNTs electrodes fabricated using a joule heating chemical vapor deposition (CVD) setup. The constructed EC contains one layer of double-sided VACNTs on graphite as bipolar electrode. Compared to a series connection of two individual devices, the bipolar EC has 22% boost in volumetric energy density. More significant boost is envisaged for stacking more bipolar electrode layers. The energy enhancement is achieved without aggravating self-discharge (71.2% retention after 1 h), and at no sacrifice of cycling stability (96.7% over 50000 cycles) owing to uniform growth of VACNTs and thus eliminating cell imbalance problems.
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| 20. |
- Hansson, Josef, 1991, et al.
(författare)
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Effects of high temperature treatment of carbon nanotube arrays on graphite : Increased crystallinity, anchoring and inter-tube bonding
- 2020
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Ingår i: Nanotechnology. - : Institute of Physics Publishing (IOPP). - 0957-4484 .- 1361-6528. ; 31:45
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Tidskriftsartikel (refereegranskat)abstract
- Thermal treatment of carbon nanotubes (CNTs) can significantly improve their mechanical, electrical and thermal properties due to reduced defects and increased crystallinity. In this work we investigate the effect of annealing at 3000 degrees C of vertically aligned CNT arrays synthesized by chemical vapor deposition (CVD) on graphite. Raman measurements show a drastically reduced amount of defects and, together with transmission electron microscope (TEM) diffraction measurements, an increased average crystallite size of around 50%, which corresponds to a 124% increase in Young's modulus. We also find a tendency for CNTs to bond to each other with van der Waals (vdW) forces, which causes individual CNTs to closely align with each other. This bonding causes a densification effect on the entire CNT array, which appears at temperatures >1000 degrees C. The densification onset temperature corresponds to the thermal decomposition of oxygen containing functional groups, which otherwise prevents close enough contact for vdW bonding. Finally, the remaining CVD catalyst on the bottom of the CNT array is evaporated during annealing, enabling direct anchoring of the CNTs to the underlying graphite substrate.
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