| 1. |
- Burman, Johan, 1966, et al.
(författare)
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A simplified method of preparing phosphoric acid for stable isotope analyses of carbonates
- 2005
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Ingår i: Rapid Communications in Mass Spectrometry. - : Wiley. - 0951-4198 .- 1097-0231. ; 19:21, s. 3086-3088
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Tidskriftsartikel (refereegranskat)abstract
- In order to produce CO2 for stable isotope analyses (delta(18)O and delta(13)C), carbonate samples are commonly digested in phosphoric acid. The acid recipe here presented is based on phase shifting crystalline orthophosphoric acid of pro-analysis quality to a liquid state through heating, followed by pre-vacuum treatment during a start-up procedure before mass analyses for common acid bath preparation, or adding a small amount of phosphoric pentoxide for single drop equipments, respectively. This methodology results in a final acid concentration of 104%. Copyright (C) 2005 John Wiley & Sons, Ltd.
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| 2. |
- Burman, Johan, 1966, et al.
(författare)
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Periwinkle (Littorina littorea) intrashell delta O-18 and delta C-13 records from the mid-Holocene Limfjord region, Denmark: a new high-resolution palaeoenvironmental proxy approach
- 2005
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Ingår i: Holocene. - : SAGE Publications. - 0959-6836 .- 1477-0911. ; 15:4, s. 567-575
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Tidskriftsartikel (refereegranskat)abstract
- Shells of the common intertidal gastropod Littorina littorea both of recent and mid-Holocene origin were analysed along their growth spirals for seasonally induced variations in stable oxygen and carbon isotope compositions. The subfossil specimens are from the Stone Age kitchen midden in Ertebolle, northern Denmark, dated between 5970 +/- 95 and 5070 +/- 90 BP The recent specimens were collected along a west-east salinity gradient within the Limfjord. A Limfjord mixing line of 0.25 parts per thousand. change in delta(18)O (V-SMOW) for each salinity unit was determined. The recent Littorina periwinkles display a calcite relationship of - 0.22 parts per thousand change in shell delta(18)O per degrees C change in temperature, as derived from the Littorina equilibrium equation (versus V-PDB): delta(18)O((Littorina)) - delta(18)O((water)) = 5.250 - 0.224T (degrees C). By using this linearity together with maximum ('winter') isotopic results, we extracted a Littorina growth stop isotherm equivalent to a temperature of 3.7 +/- 1 degrees C. In order to constrain the climate and salinity in the Limfjord region during the mid-Holocene, we used this regression-derived growth stop isotherm as a boundary condition. The subfossil shells indicate a summer surface-water temperature close to 22 +/- 1 degrees C together with a salinity of 31 +/- 1 PSU. These results suggest a more pronounced water exchange between the central Limfjord and the North Sea during the late Atlantic time, and in terms of temperature they indicate 2-4 degrees C warmer conditions than today.
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| 3. |
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| 4. |
- Schmitz, Birger, et al.
(författare)
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Extraterrestrial chromite in Middle Ordovician marine limestone at Kinnekulle, southern Sweden - Traces of a major asteroid breakup event
- 2006
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Ingår i: Meteoritics & Planetary Science. - 1086-9379. ; 41:3, s. 455-466
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Tidskriftsartikel (refereegranskat)abstract
- The distribution of sediment-dispersed extraterrestrial chromite grains and other Cr-rich spinels (> 63 mu m) has been studied in Middle Ordovician Orthoceratite Limestone from two quarries at Kinnekulle, southern Sweden. In the Thorsberg quarry, all similar to 3.2 m thick sequence of beds previously shown to be rich in fossil meteorites is also rich in sediment-dispersed extraterrestrial chromite grains. Typically, 1-3 grains are found per kilogram of limestone. In the nearby Hallekis quarry, the same beds show similarly high concentrations of extraterrestrial chromite grains, but in samples representing the 9 m downward continuation of the section exposed at this site, only 5 such grains were found in a total of 379 kg of limestone. The extraterrestrial (equilibrated ordinary chondritic) chromite grains call be readily distinguished by a homogeneous and characteristic major element chemistry, including 2.0-3.5 wt% TiO2 and stable V2O3 concentrations close to 0.7 wt%. Terrestrial Cr-rich spinels have a wide compositional range and co-exist with extraterrestrial chromite in some beds. These grains may be derived, for example, from mafic dykes exposed and weathered at the sea floor. Considering lithologic and stratigraphic aspects variations in sedimentation rate cannot explain the dramatic increase in extraterrestrial chromite seen in the upper part of the composite section studied. Instead, the difference may be primarily related to all increase in the ancient flux or extraterrestrial matter to Earth in connection with the disruption of the L chondrite parent body in the asteroid belt at about this time. The coexistence in some beds of high concentrations of chondritic chromite and terrestrial Cr-rich spinels, however, indicates that redistribution of heavy minerals on the sea floor, related to changes in sea level and sea-floor erosion and currents, must also be considered.
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| 5. |
- Boschi, Samuele, et al.
(författare)
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Late Eocene 3He and Ir anomalies associated with ordinary chondritic spinels
- 2017
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Ingår i: Geochimica et Cosmochimica Acta. - : Elsevier BV. - 0016-7037. ; 204, s. 205-218
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Tidskriftsartikel (refereegranskat)abstract
- During the late Eocene there was an enigmatic enhancement in the flux of extraterrestrial material to Earth. Evidence comes from sedimentary 3He records indicating an increased flux of interplanetary dust during ca. 2 Myr, as well as two very large impact structures, Popigai (100 km diameter) and Chesapeake Bay (40–85 km), that formed within 10–20 kyr at the peak of the 3He delivery. The Massignano section in Italy has one of the best sedimentary records of these events, including a well-defined 3He record, an Ir-rich ejecta bed related to the Popigai impact event, and two smaller Ir anomalies. Recently we showed that the Popigai ejecta is associated with a significant enrichment of chromite grains (>63 μm) with an H-chondritic elemental composition (17 grains in 100 kg of rock). Most likely these grains are unmelted fragments from the impactor. Slightly higher up (ca. 20 cm) in the section, where a small Ir anomaly possibly related to the Chesapeake Bay impact has been measured, we found a weak enrichment in L-chondritic grains (8 grains in 208 kg of rock). Here we report an extended data set increasing the total amount of sediment dissolved in acid and searched for extraterrestrial chromite grains from 658 to 1168 kg. In altogether 760 kg of background sediment from 17 levels over 14 m of strata outside the interval corresponding to the Popigai and Chesapeake Bay impacts, we only found 2 extraterrestrial chromite grains. Both grains have L-chondritic compositions and were found in a 100 kg sample from the ca. 10.25 m level in the section where the second of the smaller Ir anomalies has been reported. A correlation appears to exist between Ir, 3He and chromite from ordinary chondrites. We also report oxygen three-isotope measurements of the extraterrestrial chromite grains associated with the Popigai ejecta and confirm an H-chondritic composition. The new results strengthen our scenario that the upper Eocene 3He and Ir enrichments originate from the asteroid belt rather than the Oort cloud as originally proposed when the 3He anomaly was discovered. The generally low background concentrations of extraterrestrial chromite through the section speak against any major single asteroid breakup event such as in the mid-Ordovician after the break-up of the L-chondrite parent body. Instead the data reconcile with a small, possibly a factor of 2–3, increase in the flux of extraterrestrial material to Earth, but of both H- and L-chondritic composition. We also report the composition of all the 2310 terrestrial chrome spinel grains recovered, and show that their chemical composition indicates a dominantly regional ophiolitic source. Four anomalous chrome spinel grains with high Ti and V concentrations were found in the Popigai ejecta. These grains originate from Siberian Traps basalts in the Popigai crater at the time of impact.
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| 6. |
- Aguirre-Palafox, Erick Luis, et al.
(författare)
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Zircon provenance analysis from Lower Paleocene pelagic limestones of the Bottaccione section at Gubbio (Umbria-Marche basin, Italy)
- 2019
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Ingår i: Geological Society of America. Special Papers. - : Geological Society of America. - 0072-1077. ; 542
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Tidskriftsartikel (refereegranskat)abstract
- Dating detrital zircon grains from sands and sandstones has become an important geological technique for determining sediment provenance and dispersal patterns. Here, we report what we believe to be the first provenance study of zircon grains extracted by dissolving large samples of pelagic limestone. Our samples come from the Paleocene section of the Umbria-Marche Apennines, Italy. Recovery of these zircon grains was a fortunate by-product of a study on chromite grains aimed to determine the kinds of meteorites that have fallen on Earth through time. The zircons we recovered included both euhedral crystals interpreted as airborne ash from volcanic eruptions of the same age as the sediment in which they were found, and rounded grains interpreted as windblown detrital material with a history of sediment transport, probably derived from desert regions. This study focuses on the rounded grains, to provide constraints on the source region from which they came.Samples from five levels in the 12 m immediately above the Cretaceous-Paleogene boundary at Gubbio, Italy, yielded detrital zircon grains with ages clustered in eight bands extending back to the Neoarchean. A previous study of this outcrop using proxies for the noncarbonate detrital content had suggested a source region for this dust either in North Africa or in Central Asia. A comparison of our dates from the actual dust grains to geochronological studies from the literature suggests source regions in North Africa and/or the Iberian Peninsula, rather than in Central Asia. In reaching this conclusion, we considered the orogenic events that may have produced each of the eight age bands, the specific source regions that may have supplied zircons from each age group, and the implications for paleoclimate (especially aridity) and paleowind conditions for the few million years just after the Cretaceous-Paleogene boundary.
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| 7. |
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| 8. |
- Ahlberg, Per, et al.
(författare)
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Maurits Lindström 1932-2009
- 2011
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Ingår i: Kungliga Fysiografiska Sällskapet i Lund Årsbok 2009-2010. - 1402-1277. ; 2009-2010, s. 138-140
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Bokkapitel (refereegranskat)
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| 9. |
- Albanesi, Guillermo L., et al.
(författare)
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Darriwilian (Middle Ordovician) delta C-13(carb) chemostratigraphy in the Precordillera of Argentina: Documentation of the middle Darriwilian Isotope Carbon Excursion (MDICE) and its use for intercontinental correlation
- 2013
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Ingår i: Palaeogeography, Palaeoclimatology, Palaeoecology. - : Elsevier BV. - 1872-616X .- 0031-0182. ; 389, s. 48-63
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Tidskriftsartikel (refereegranskat)abstract
- Although documented from Estonia, Latvia, Sweden, eastern North America, and China, the Middle Ordovician (Darriwilian) positive delta C-13 excursion known as the MDICE has previously not been recognized with certainty in South America. The most promising region in South America for detailed Middle Ordovician carbon isotope research is the Precordillera of western Argentina, where there are many excellent exposures of biostratigraphically well-dated carbonate successions spaning the Tremadocian through Sandbian stratigraphic interval. For this project, we collected numerous isotope and conodont samples from the middle Darriwilian Las Chacritas and Aguaditas formations at their type localities, which yielded important biostratigraphic data as well as informative delta C-13(carb) values. In the E. pseudoplanus Zone in the upper half of the Las Chacritas Formation, there is a relatively modest but distinct delta C-13(carb) excursion. Because its stratigraphic position and magnitude closely agree with the MDICE in other parts of the world, we recognize it as the first firm record of this excursion in South America. The fact that the delta C-13(carb) curve from the Las Aguaditas Formation shows no such excursion is due to the existence of a stratigraphic gap between the Lower and Middle Members of this formation that cuts out the excursion interval. The Precordilleran MDICE is used for detailed long-range correlations with successions in Baltoscandia, Newfoundland, and China illustrating the usefulness of also this delta C-13(carb) excursion as a global stratigraphic tool. A recent proposal of a greatly extended chronostratigraphic range of the Table Head Group on Newfoundland is rejected based on well-established biostratigraphic evidence. (C) 2013 Elsevier B.V. All rights reserved.
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| 10. |
- Alwmark, Carl, et al.
(författare)
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A 3-D study of mineral inclusions in chromite from ordinary chondrites using synchrotron radiation X-ray tomographic microscopy-Method and applications
- 2011
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Ingår i: Meteoritics and Planetary Science. - : Wiley. - 1086-9379. ; 46:8, s. 1071-1081
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Tidskriftsartikel (refereegranskat)abstract
- A method is described for imaging in 3-D the interiors of meteoritic chromite grains and their inclusions using synchrotron radiation X-ray tomographic microscopy. In ordinary chondrites, chromite is the only common mineral that survives long-term weathering on Earth. Information about the silicate matrix of the original meteorite, however, can be derived from mineral inclusions preserved in the protecting chromite. The inclusions are crucial in the classification of fossil meteorites as well as sediment-dispersed chromite grains from decomposed meteorites and larger impacts, as these are used for characterizing the past influx of material to Earth, but have previously been difficult to locate. The method is non-destructive and time efficient for locating inclusions. The method allowed quantitative and morphological studies of both host chromite grains and inclusions in three dimensions. The study of 385 chromite grains from eight chondrites (H4-6, L4-6, LL4, LL6) reveals that inclusions are abundant and equally common in all samples. Almost two-thirds of all chromite grains contain inclusions, regardless of group and type. The study also shows that the size of the inclusions and the host chromite grains, as well as the number of inclusions, within the host chromite grains vary with petrographic type. Thus, the petrographic type of the host of a suite of chromite grains can be determined based solely on inclusion content. The study also revealed that the amount of fractures in the host chromite can be correlated to previously assigned shock stages for the various chondrites. The study has thus shown that the features and inclusions of fossil chromite grains can give similar information about a former host meteorite as do studies of an unweathered whole meteorite, meaning that this technique is essential in the studies of ancient meteorite flux to Earth.
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