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Sökning: hsv:(TEKNIK OCH TEKNOLOGIER) hsv:(Industriell bioteknik) > Linköpings universitet

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1.
  • Gustafsson, Marcus, 1987-, et al. (författare)
  • Climate performance of liquefied biomethane with carbon dioxide utilization or storage
  • 2024
  • Ingår i: Renewable and sustainable energy reviews. - : Elsevier. ; 192
  • Tidskriftsartikel (refereegranskat)abstract
    • In the process of upgrading biogas to biomethane for gas grid injection or use as a vehicle fuel, biogenic carbon dioxide (CO₂) is separated and normally emitted to the atmosphere. Meanwhile, there are a number of ways of utilizing CO₂ to reduce the dependency on fossil carbon sources. This article assesses the climate performance of liquefied biomethane for road transport with different options for utilization or storage of CO₂. The analysis is done from a life cycle perspective, covering the required and avoided processes from biogas production to the end use of biomethane and CO₂. The results show that all of the studied options for CO₂ utilization can improve the climate performance of biomethane, in some cases contributing to negative CO₂ emissions. One of the best options, from a climate impact perspective, is to use the CO₂ internally to produce more methane, although continuous supply of hydrogen from renewable sources can be a challenge. Another option that stands out is concrete curing, where CO₂ can both replace conventional steam curing and be stored for a long time in mineral form. Storing CO₂ in geological formations can also lead to negative CO₂ emissions. However, with such long-term storage solutions, opportunities to recycle biogenic CO₂ are lost, together with the possibility of de-fossilizing processes that require carbon, such as chemical production and horticulture.
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2.
  • Gustafsson, Marcus, 1987-, et al. (författare)
  • Värdeskapande av koldioxid från biogasproduktion
  • 2023
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • Koldioxid (CO₂) har en negativ påverkan på klimatet, men har även många praktiska användningsområden. Många industriella processer släpper ut CO₂ i höga koncentrationer som skulle kunna fångas in för att begränsa emissioner och samtidigt skapa värdefulla produkter. Ett exempel på en sådan process är biogasuppgradering – en separationsprocess av förnybara gaser, där metan tas till vara för användning som fordonsbränsle eller energibärare inom industri, medan CO₂ släpps ut i atmosfären. Syftet med detta projekt har varit att kartlägga möjligheter och tekniker för att tillvarata grön CO₂ från biogasproduktion, så kallad carbon capture and utilization (CCU), samt att utreda förutsättningar för att tillämpa dessa i en svensk kontext. Arbetet har vägletts av följande frågeställningar:Hur stor är den nuvarande och framtida potentialen för CCU från biogasproduktion?Vilka möjliga användningsområden finns det för CO₂ från biogasproduktion?Vilka faktorer påverkar valet av användningsområde för CO₂ från biogasproduktion?Hur stor är den miljömässiga nyttan av CCU från biogasproduktion?För att besvara dessa frågeställningar genomfördes potentialberäkningar, multikriterieanalys och livscykelanalys, med utgångspunkt i svensk biogasproduktion. En referensgrupp bestående av representanter för stora svenska företag inom biogasproduktion och teknik för biogasuppgradering användes för att möjliggöra samproduktion och nätverkande mellan forskargruppen och branschen.Produktionen av CO₂ från biogas uppskattades till 160 000 ton/år 2020, med potential att öka till 540 000 – 840 000 ton/år på medellång sikt och 790 000 – 1 230 000 ton/år på lång sikt, som en följd av en förmodad ökning av biogasproduktionen i Sverige. En stor del av koldioxiden produceras dock vid relativt små uppgraderingsanläggningar, vilket kan begränsa möjligheten att tillämpa CCU på grund av höga investerings- och driftskostnader. Att tillföra vätgas för att omvandla all CO₂ till metan skulle potentiellt kunna öka metanproduktionen från biogas från 2 till 3 TWh/år på kort sikt och från 11 till 17 TWh/år på lång sikt, förutsatt tillräckligt stor tillgång på vätgas.Andra sätt att använda CO₂ från biogas innefattar bland annat produktion av biomassa eller kemikalier, härdning av betong, pH-reglering av processvatten och användning som köldmedium. Valet av CCU- alternativ kan påverkas av miljömässiga, tekniska, ekonomiska och policyrelaterade aspekter. Ur biogasproducenternas perspektiv är metanisering det som är mest kompatibelt med det befintliga produktionssystemet och affärsmodellen, medan andra lösningar oftast innebär att en annan aktör tar hand om koldioxiden. Vätgas behövs för såväl metanisering som produktion av kemikalier. En annan begränsande faktor är höga renhetskrav på all CO₂ som distribueras och säljs på marknaden. Den geografiska spridningen på anläggningarna kan också vara en utmaning.Många CCU-alternativ kan förbättra biogasens miljöprestanda genom att ersätta fossilbaserade produkter. Klimatpåverkan blir lägst om koldioxiden metaniseras med förnybar vätgas eller mineraliseras i betong, men även andra former av miljöpåverkan kan minskas genom att tillämpa dessa eller andra CCU-alternativ. Som jämförelse kan permanent lagring av CO₂ i geologiska formationer (carbon capture and storage, CCS) endast minska klimatpåverkan, medan det ökar övriga typer av miljöpåverkan. Samtidigt kan permanent lagring av biogen CO₂ göra det svårare att minska användningen av fossil CO₂ och ställa om till ett mer hållbart samhälle. Behovet av kol i många viktiga processer och produkter talar för att biogen CO₂ bör användas och inte lagras.
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3.
  • Hagman, Linda, 1991-, et al. (författare)
  • Assessment of By-product Valorisation in a Swedish Wheat-Based Biorefinery
  • 2020
  • Ingår i: Waste and Biomass Valorization. - : Springer Netherlands. - 1877-2641 .- 1877-265X. ; 11:7, s. 3567-3577
  • Tidskriftsartikel (refereegranskat)abstract
    • Biorefineries are examples of industries striving towards a circular and bio-based economy through valorising natural raw materials to a spectrum of products. This is a resource-efficient process which also decreases overall environmental impact, as the products from a biorefinery can replace fossil-based products such as plastics or fuels. To become even more resource efficient, an optimisation of the by-product use can increase the performance. This study will evaluate different scenarios for the valorisation of stillage coming from a wheat-based biorefinery. The alternatives range from the direct use of the stillage for fodder, fertiliser or incineration to three different biogas production-based scenarios. The biogas scenarios are divided into the production of fuel at a local or distant plant and the alternative of creating heat and power at the local plant. The results show how locally produced biogas for vehicle fuel and fodder usage are the better alternatives regarding greenhouse gas emissions, the finances of the biorefinery, energy balance and nutrient recycling. The results also indicate that biorefineries with several high-value products may receive lower quality by-product flows, and to these, the biogas solutions become more relevant for valorising stillage while improving value and performance for the biorefinery.
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4.
  • Hagman, Linda, 1991- (författare)
  • How do biogas solutions influence the sustainability of bio-based industrial systems?
  • 2018
  • Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Biomass is a valuable and limited resource that should be used efficiently. The potential of replacing fossil-based products with bio-based ones produced in biobased industrial systems is huge. One important aim of increasing the share of biobased products is to improve the sustainability of systems for production and consumption. Therefore, it is important to evaluate what solutions are available to improve the sustainability performance of bio-based industrial systems, and if they also bring negative impacts. The thesis focuses on assessing the role of biogas solutions in developing sustainable bio-based systems. Such assessments are often quite narrow in their scope and focus on quantitative environmental or economic aspects. This thesis aims at also including feasibility related aspects involving the contextual conditions that are assessed more qualitatively. Biogas solutions are identified as a versatile approach to treat organic materials which are generated in large volumes in bio-based industrial systems. The results show that biogas solutions in bio-based industrial systems (i) improve circular flows of energy and nutrients, (ii) are especially viable alternatives when the quality of the by-product streams become poorer, and (iii) may improve the profitability of the bio-based industrial system. To perform better assessments of these systems, it seems valuable to broaden the set of indicators assessed and include feasibility-related indicators, preferably through the involvement of relevant stakeholders as they contribute with different perspectives and can identify aspects that influence the sustainability in different areas. Future studies could benefit from applying those broader assessments on more cases to build on a more generalisable knowledge base.
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5.
  • Parker, Daniela, et al. (författare)
  • Biohybrid plants with electronic roots via in vivo polymerization of conjugated oligomers
  • 2021
  • Ingår i: Materials Horizons. - : Royal Society of Chemistry. - 2051-6347 .- 2051-6355. ; 8:12, s. 3295-3305
  • Tidskriftsartikel (refereegranskat)abstract
    • Plant processes, ranging from photosynthesis through production of biomaterials to environmental sensing and adaptation, can be used in technology via integration of functional materials and devices. Previously, plants with integrated organic electronic devices and circuits distributed in their vascular tissue and organs have been demonstrated. To circumvent biological barriers, and thereby access the internal tissue, plant cuttings were used, which resulted in biohybrids with limited lifetime and use. Here, we report intact plants with electronic functionality that continue to grow and develop enabling plant-biohybrid systems that fully maintain their biological processes. The biocatalytic machinery of the plant cell wall was leveraged to seamlessly integrate conductors with mixed ionic-electronic conductivity along the root system of the plants. Cell wall peroxidases catalyzed ETE-S polymerization while the plant tissue served as the template, organizing the polymer in a favorable manner. The conductivity of the resulting p(ETE-S) roots reached the order of 10 S cm(-1) and remained stable over the course of 4 weeks while the roots continued to grow. The p(ETE-S) roots were used to build supercapacitors that outperform previous plant-biohybrid charge storage demonstrations. Plants were not affected by the electronic functionalization but adapted to this new hybrid state by developing a more complex root system. Biohybrid plants with electronic roots pave the way for autonomous systems with potential applications in energy, sensing and robotics.
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6.
  • Anderson, Henrik, et al. (författare)
  • Systematic investigation of biomolecular interactions using combined frequency and motional resistance measurements
  • 2011
  • Ingår i: Sensors and actuators. B, Chemical. - : Elsevier BV. - 0925-4005 .- 1873-3077. ; 153:1, s. 135-144
  • Tidskriftsartikel (refereegranskat)abstract
    • The resonance frequency of acoustic biosensors is today used as a label-free technique for detecting mass changes on sensor surfaces. In combination with an appropriate continuous flow system it has earlier been used for affinity and kinetic rate determination. Here, we assess the potential of a modified acoustic biosensor, monitoring also the real-time dissipation through the resistance of the sensor, to obtain additional kinetic information related to the structure and conformation of the molecules on the surface. Actual interaction studies, including an attempt to determine avidity, are presented along with thorough verification of the experimental setup utilizing true viscous load exposure together with protein and DNA immobilizations. True viscous loads show a linear relationship between resistance and frequency as expected. However, in the interaction studies between antibodies and proteins, as well as in the immobilization of DNA and proteins, higher surface concentrations of interacting molecules led to a decrease (i.e. deviation from the linear trend) in the differential resistance to frequency ratio. This is interpreted as increased surface rigidity at higher surface concentrations of immobilized molecules. Consequently, studies that aim at obtaining biological binding information, such as avidity, from real-time resistance and dissipation data should be conducted at low surface concentrations. In addition, the differential resistance to frequency relationship was found to be highly dependent on the rigidity of the preceding layer(s) of immobilized molecules. This dependence can be utilized to obtain a higher signal-to-noise ratio for resistance measurement by using low surface densities of immobilized interaction partners.
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7.
  • Ekstrand, Eva-Maria, et al. (författare)
  • Viscosity dynamics and the production of extracellular polymeric substances and soluble microbial products during anaerobic digestion of pulp and paper mill wastewater sludges
  • 2020
  • Ingår i: Bioprocess and biosystems engineering (Print). - : SPRINGER. - 1615-7591 .- 1615-7605. ; 43:2, s. 283-291
  • Tidskriftsartikel (refereegranskat)abstract
    • The production processes of the pulp and paper industry often run in campaigns, leading to large variations in the composition of wastewaters and waste sludges. During anaerobic digestion (AD) of these wastes, the viscosity or the production of extracellular polymeric substances (EPS) and soluble microbial products (SMP) may be affected, with the risk of foam formation, inefficient digester mixing or poor sludge dewaterability. The aim of this study was to investigate how viscosity and production of EPS and SMP during long-term AD of pulp and paper mill sludge is affected by changes in organic loading rate (OLR) and hydraulic retention time (HRT). Two mesophilic lab-scale continuous stirred tank reactors (CSTRs) were operated for 800 days (R1 and R2), initially digesting only fibre sludge, then co-digesting fibre sludge and activated sludge. The HRT was lowered, followed by an increase in the OLR. Reactor fluids were sampled once a month for rheological characterization and analysis of EPS and SMP. The production of the protein fraction of SMP was positively correlated to the OLR, implicating reduced effluent qualities at high OLR. EPS formation correlated with the magnesium content, and during sulphate deficiency, the production of EPS and SMP increased. At high levels of EPS and SMP, there was an increase in viscosity of the anaerobic sludges, and dewatering efficiency was reduced. In addition, increased viscosity and/or the production of EPS and SMP were important factors in sludge bulking and foam formation in the CSTRs. Sludge bulking was avoided by more frequent stirring.
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8.
  • Lindbergh, Tobias, et al. (författare)
  • Reduced scattering coefficient determination by non-contact oblique angle illumination: methodological considerations
  • 2007
  • Ingår i: Proceedings of SPIE, the International Society for Optical Engineering. - : SPIE. - 0277-786X .- 1996-756X. ; 6435, s. 64350I-1-64350I-12
  • Tidskriftsartikel (refereegranskat)abstract
    • The reduced scattering coefficient, µs, was determined using oblique angle illumination and imaging backscattered light intensity. The distance r between the point of light incidence (hot-spot) and the circular symmetric diffuse reflectance centre, is ~1/µ. Previously, r was obtained analyzing a 1D strip aligned with the laser beam. We improved this method by calculating a 2D intensity image with extended dynamic range by assessing camera linearity, superimposing images with multiple integration times, and compensating for lens vignetting. The hot-spot algorithm utilises several images to minimize speckle variations and account for laser beam shape. Diffuse centre position is obtained by filtering the superimposed image with decreasing thresholds using momentum analysis to determine circular symmetry. The method was evaluated on 18 optical liquid phantoms with µs[1.5, 3.0] mm-1 and µs[0.01, 0.16] mm-1. The 2D method had better linearity with µs and smaller variations due to more stable hot-spot detection, than the 1D method. The anisotropy factor g was obtained by fitting measured and Monte Carlo simulated spatially resolved intensity decays and verified with a laser Doppler flowmetry technique. With an optimal compensation for the µa dependence, the rms error in µ estimation was 2.9%.
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9.
  • Pei, Zhichao, et al. (författare)
  • Optimizing immobilization on two-dimensional carboxyl surface : pH dependence of antibody orientation and antigen binding capacity
  • 2010
  • Ingår i: Analytical Biochemistry. - : Elsevier BV. - 0003-2697 .- 1096-0309. ; 398:2, s. 161-168
  • Tidskriftsartikel (refereegranskat)abstract
    • The performance of immunosensors is highly dependent on the amount of immobilized antibodies and their remaining antigen binding capacity. In this work, a method for immobilization of antibodies on a two dimensional carboxyl surface has been optimized using quartz crystal microbalance biosensors. We have shown that successful immobilization is highly dependent on surface pKa, antibody pI and pH of immobilization buffer. By use of EDC/sulfo-NHS activation reagents, the effect of the intrinsic surface pKa is avoided and immobilization also at very low pH has been made possible which is of importance for immobilization of acidic proteins. Generic immobilization conditions were demonstrated on a panel of antibodies which resulted in an average coefficient of variation of 4% for the immobilization of these antibodies. Antigen binding capacity as a function of immobilization pH was studied. In most cases the antigen binding capacity followed the immobilization response. However, the antigen to antibody binding ratio differed between the antibodies investigated, and for one of the antibodies, the antigen binding capacity was significantly lower than expected from immobilization in a certain pH range. Tests with anti-Fc and anti-Fab antibodies on different antibody surfaces showed that the orientation of the antibodies on the surface had a profound effect on the antigen binding capacity of the immobilized antibodies.
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10.
  • Welin, Stellan, 1947-, et al. (författare)
  • In vitro meat – What are the moral issues?
  • 2012
  • Ingår i: The Philosophy of Food, ed. David Kaplan, University of California Press. - Berkeley, California : University of California Press. ; , s. 292-304, s. 292-304
  • Bokkapitel (övrigt vetenskapligt/konstnärligt)
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