Sökning: id:"swepub:oai:research.chalmers.se:74ea798c-7b32-4db5-83b4-72f830dc043a" >
Selective Iron-Medi...
Selective Iron-Mediated C- and O-Addition of Phenolic Nucleophiles to a Cyclohexadiene Scaffold Using Renewable Precursors
-
- Dunås, Petter, 1990 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Paterson, Andrew, 1988 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Kociok-Köhn, G. (författare)
- University of Bath
-
visa fler...
-
- Lewis, Simon E. (författare)
- University of Bath
-
- Kann, Nina, 1964 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
-
visa färre...
-
(creator_code:org_t)
- 2019-02-28
- 2019
- Engelska.
-
Ingår i: ACS Sustainable Chemistry & Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 7:7, s. 7155-7162
- Relaterad länk:
-
https://research.cha... (primary) (free)
-
visa fler...
-
https://pubs.acs.org...
-
https://doi.org/10.1...
-
https://research.cha...
-
visa färre...
Abstract
Ämnesord
Stäng
- Renewable phenols have been investigated as nucleophiles for the addition to a cationic cyclohexadienyl iron carbonyl scaffold. Benign conditions compatible with solvents such as ethanol and water were developed, and for the first time, selective C- or O-addition could be achieved. In addition, a novel atom-economic approach to forming the C-addition products directly from the neutral precursor complex in a single step using a catalytic acid is described. The formed C-addition product could then be selectively demetalated to form one of two different product classes, a functionalized arene or a cyclohexadiene.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Industriell bioteknik -- Biokatalys och enzymteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Industrial Biotechnology -- Biocatalysis and Enzyme Technology (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- Water
- Iron
- Renewable resources
- Cyclohexadiene
- Metal carbonyl
- Green chemistry
- Phenols
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
Hitta via bibliotek
Till lärosätets databas