Functionalised N-Heterocyclic Carbene Complexes

• Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; Chapter 2 Why Functionalisation?; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups; Chapter 5 Chiral N-Heterocyclic Carbenes; Chapter 6 Natural Products; Index. 

• N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin

Ämnesord

Heterocyclic compounds. 

Ligands. 

Transition metal complexes. 

Genre

Electronic books.  (LCSH)

Publikations- och innehållstyp

QD474 .K825 2010 (LCC)

541.2242 (DDC)

Uceeb (kssb/8 (machine generated))