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Expanding the scope...
Expanding the scope of the elpaN-type library : glucose-derived bis(pyridine-2-carboxamide) ligands (elpaN-Py) for molybdenum-catalyzed asymmetric allylic alkylations
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- Lega, Matteo (författare)
- KTH,Organisk kemi
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Figliolia, Rosario (författare)
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- Moberg, Christina (författare)
- KTH,Organisk kemi
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Ruffo, Francesco (författare)
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(creator_code:org_t)
- Elsevier BV, 2013
- 2013
- Engelska.
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Ingår i: Tetrahedron. - : Elsevier BV. - 0040-4020 .- 1464-5416. ; 69:20, s. 4061-4065
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The elpaN-Py family of ligands, which represents a subset of the elpaN-type library based on a-glucose, is described. The ligands are structural analogs of the privileged bis(pyridine-2-carboxamides) derived from trans-1,2-diaminocyclohexane, and differ for the type of substitution in the coordinating functions present in positions 1 and 2. Their ability to induce high enantioselectivity in asymmetric allylic alkylations promoted by molybdenum under microwave irradiation has been successfully demonstrated, starting from both a linear (ee up to 99%) and a branched substrate (ee up to 96%). The multifunctional nature of the sugar scaffold was exploited for the preparation of a polar ligand, through deprotection of the hydroxyl groups in positions 3, 4 and 6. In this version, it was possible to verify the performance in catalysis in alternative solvents, such as ionic liquids and water.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- Asymmetric catalysis
- Molybdenum
- Carbohydrates
- Allylation
- Microwave reactions
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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