Sökning: onr:"swepub:oai:DiVA.org:kth-155466" > Nickel Complex with...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 02827naa a2200433 4500 | |
001 | oai:DiVA.org:kth-155466 | |
003 | SwePub | |
008 | 141106s2014 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1554662 URI |
024 | 7 | a https://doi.org/10.1002/cssc.2014023812 DOI |
040 | a (SwePub)kth | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Yang, Yong4 aut |
245 | 1 0 | a Nickel Complex with Internal Bases as Efficient Molecular Catalyst for Photochemical H-2 Production |
264 | c 2014-09-01 | |
264 | 1 | b Wiley,c 2014 |
338 | a print2 rdacarrier | |
500 | a QC 20141113 | |
520 | a A Ni complex with internal bases that contain bipyridine-derived ligands, [Ni(L)(2)(H2O)(2)](BF4)(2) ([1](BF4)(2), L=2-(2-pyridyl)-1,8-naphthyridine), and a reference complex that bears analogous bipyridine-derived ligands but without an internal base, [Ni(L)(3)](BF4)(2) ([2](BF4)(2), L=2-(2-pyridyl)quinoline), were synthesized and characterized. The electrochemical properties of these complexes were studied in CH3CN, H2O, and a mixture of EtOH/H2O. The fluorescence spectroscopic studies suggest that both dynamic and the sphere-of-action static quenching exist in the fluorescein Fl(2-)/[1](2+) and Fl(2-)/[2](2+) systems. These noble-metal-free molecular systems were studied for photocatalytic H-2 generation. Under optimal conditions, the turnover number of H-2 evolution reaches 3230 based on [1](2+), whereas [2](2+) displays only approximately one third of the turnover of [1](2+). A plausible mechanism for the catalytic H-2 generation by [1](2+) is presented based on DFT calculations. | |
650 | 7 | a NATURVETENSKAPx Kemix Annan kemi0 (SwePub)104992 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Other Chemistry Topics0 (SwePub)104992 hsv//eng |
653 | a density functional calculations | |
653 | a hydrogen | |
653 | a nickel | |
653 | a photochemistry | |
653 | a water splitting | |
700 | 1 | a Wang, Mei4 aut |
700 | 1 | a Xue, Liqinu KTH,Teoretisk kemi och biologi4 aut0 (Swepub:kth)u10eykwn |
700 | 1 | a Zhang, Fengbo4 aut |
700 | 1 | a Chen, Lin4 aut |
700 | 1 | a Ahlquist, Mårten S. G.u KTH,Teoretisk kemi och biologi4 aut0 (Swepub:kth)u1agoeae |
700 | 1 | a Sun, Lichengu KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, DUT-KTH Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), China4 aut0 (Swepub:kth)u1umfd9h |
710 | 2 | a KTHb Teoretisk kemi och biologi4 org |
773 | 0 | t ChemSusChemd : Wileyg 7:10, s. 2889-2897q 7:10<2889-2897x 1864-5631x 1864-564X |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-155466 |
856 | 4 8 | u https://doi.org/10.1002/cssc.201402381 |
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
Kopiera och spara länken för att återkomma till aktuell vy