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Synthesis of chiral...
Synthesis of chiral salen Mn(III) complexes covalently linked to Re(I)-based photosensitizers
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Chen, Y. G. (författare)
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Wang, M. (författare)
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Jin, K. (författare)
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Wang, D. P. (författare)
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Na, Y. (författare)
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Sun, Licheng C. (författare)
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- 2006-08-21
- 2006
- Engelska.
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Ingår i: Journal of coordination chemistry (Print). - : Informa UK Limited. - 0095-8972 .- 1029-0389. ; 59:5, s. 475-484
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied.
Nyckelord
- manganese complex
- rhenium complex
- heterobinuclear complex
- chiral salen ligand
- pyrrolidine
- light-driven catalyst
- tricarbonylrhenium(i) halide-complexes
- intramolecular electron-transfer
- stereochemical rearrangements
- photophysical properties
- solution stereodynamics
- carbonyl-complexes
- tris-bipyridine
- ligand
- rhenium(i)
- epoxidation
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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