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Use of two-dimensio...
Use of two-dimensional photoelectron spectroscopy in the decomposition of an inner-shell excitation spectrum broadened by super-Coster-Kronig decay
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- Kivimäki, A. (författare)
- CNR, Italy
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- Norman, P. (författare)
- Linköpings universitet,Beräkningsfysik,Tekniska högskolan
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- Coreno, M. (författare)
- CNR, Italy
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- De Simone, M. (författare)
- CNR, Italy
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- Grazioli, C. (författare)
- Elettra Sincrotrone Trieste, Italy
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- Totani, R. (författare)
- University of Aquila, Italy
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- Ressel, B. (författare)
- University of Nova Gorica, Slovenia
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- Ottosson, Henrik (författare)
- Uppsala universitet,Fysikalisk-organisk kemi,Uppsala University, Sweden
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- Puglia, Carla (författare)
- Uppsala universitet,Molekyl- och kondenserade materiens fysik,Uppsala University, Sweden
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(creator_code:org_t)
- American Physical Society, 2013
- 2013
- Engelska.
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 88:6
- Relaterad länk:
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https://liu.diva-por... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- The Ge 3p core excitation spectrum of the n-butylgermane molecule only reveals two peaks, whereas the rest of the fine structure is obscured due to the large lifetime broadenings of core-excited states. A two-dimensional presentation of resonant photoemission spectra allows us to observe some other resonances. The interpretation of experimental results is supported by ab initio calculations conducted at the four-component relativistic level of theory with full account made for spin-orbit interactions already in the zeroth-order Hamiltonian.
Ämnesord
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
Nyckelord
- Ab initio calculations
- Core excitation
- Core-excited state
- Fine structures
- Inner shell excitation
- Resonant photoemission
- Spin orbit interactions
- Two-dimensional photoelectron spectroscopy
- Germanium
- Hamiltonians
- Nuclear physics
- Photoelectron spectroscopy
- Two dimensional
- Excited states
- TECHNOLOGY
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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