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Electrospray ioniza...
Electrospray ionization mass spectrometry of rhenium(I) bipyridyl complexes
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Sun, S. G. (författare)
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Peng, X. J. (författare)
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Zhang, R. (författare)
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visa fler...
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Sun, Licheng C. (författare)
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visa färre...
- 2003
- 2003
- Kinesiska.
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Ingår i: Youji huaxue. - 0253-2786. ; 23:10, s. 1135-1138
- Relaterad länk:
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https://urn.kb.se/re...
Abstract
Ämnesord
Stäng
- The electrospray ionization mass spectrometry (ESI-MS) of a series of rhenium(I) bipyridyl complexes [(4,4'-(COOEt)(2)-bPY)Re(CO)(3)RPF6], where bpy is 2,2'-bipyridine and R is pyridine, 4-methylpyridine, 4-hydroxypyridine, 4-aminopyridine or 10-(4-picolyl)phenothiazine (py-PTZ) was studied. The dissociation of the ligands (R) forms the fragment of [(4, 4'-( COOEt)(2)-bpy) Re (CO)3](+) at different voltages of in-source collision induced dissociation (CID). The dissociation tendency is in an order: pyridine > 4-methylpyridine > 4-hydroxypyridine > 4-aminopyridine > py-PTZ. It might be used to deduce the stability of these complexes when they are used as photosensitizers in solar cells.
Nyckelord
- ESI-MS
- in-source CID
- rhenium(I) bipyridyl complex
- photosensitive dye
- light
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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