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Molecular engineeri...
Molecular engineering of ionic type perylenediimide dimer-based electron transport materials for efficient planar perovskite solar cells
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Chen, C. (författare)
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Cheng, M. (författare)
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Li, H. (författare)
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Qiao, F. (författare)
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- Liu, Peng (författare)
- KTH,Kemi
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- Kloo, Lars (författare)
- KTH,Kemi
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- Sun, Licheng, 1962- (författare)
- KTH,Kemi
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(creator_code:org_t)
- Elsevier Ltd, 2018
- 2018
- Engelska.
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Ingår i: Materials Today Energy. - : Elsevier Ltd. - 2468-6069. ; 9, s. 264-270
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The main of this work is to overcome the drawbacks of the traditional fullerene derivatives used as electron transport materials (ETMs) for perovskite solar cells (PSCs). Herein, a new strategy to design non-fullerene ETMs is presented by molecular engineering to include charged moieties in the ETM. The designed ETM FA2+-PDI2 is intrinsically ionic and the incorporated counter ions in FA2+-PDI2 significantly increase the electron conductivity and improve the film formation properties. Through careful device optimization, PSCs based on the ionic ETM FA2+-PDI2 exhibit an impressive average power conversion efficiency (PCE) of 17.0%, which is comparable to the PSC based on PC61BM (17.5%). The superior photovoltaic performance can be attributed to efficient electron extraction and effective electron transfer in the PSCs. This work provides important insights regarding the future design of new and efficient non-fullerene ETMs for PSCs.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Naturresursteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Environmental Engineering (hsv//eng)
Nyckelord
- Electron transport material
- Fullerene-free
- Perylenediimide
- Planar perovskite solar cell
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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