Sökning: onr:"swepub:oai:DiVA.org:kth-237128" >
Thermodynamic asses...
Thermodynamic assessment of ZnO-SiO2 system
-
- Isomaki, Iikka (författare)
- Aalto Univ, Sch Chem Technol, Dept Mat Sci & Engn, Thermodynam & Modelling Res Grp, POB 16200, FI-00076 Aalto, Finland.
-
- Zhang, Rui (författare)
- KTH,Materialvetenskap
-
- Xia, Long-gong (författare)
- Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China.
-
visa fler...
-
- Hellsten, Niko (författare)
- Aalto Univ, Sch Chem Technol, Dept Mat Sci & Engn, Thermodynam & Modelling Res Grp, POB 16200, FI-00076 Aalto, Finland.
-
- Taskinen, Pekka A. (författare)
- Aalto Univ, Sch Chem Technol, Dept Mat Sci & Engn, Thermodynam & Modelling Res Grp, POB 16200, FI-00076 Aalto, Finland.
-
visa färre...
-
Aalto Univ, Sch Chem Technol, Dept Mat Sci & Engn, Thermodynam & Modelling Res Grp, POB 16200, FI-00076 Aalto, Finland Materialvetenskap (creator_code:org_t)
- Elsevier, 2018
- 2018
- Engelska.
-
Ingår i: Transactions of Nonferrous Metals Society of China. - : Elsevier. - 1003-6326 .- 2210-3384. ; 28:9, s. 1869-1877
- Relaterad länk:
-
https://urn.kb.se/re...
-
visa fler...
-
https://doi.org/10.1...
-
visa färre...
Abstract
Ämnesord
Stäng
- ZnO-containing slags are common in pyrometallurgical processing of the base metals and steel. This caused the interest to the thermodynamics of the ZnO-SiO2 system. A complete literature survey, critical evaluation of the available experimental data and a thermodynamic optimization of the phase equilibria and thermodynamic properties of the system ZnO-SiO2 at 1.013x10(5) Pa are presented. The molten oxide was described as an associate solution. The properties of liquid were reassessed and enthalpy term of the Gibbs energy of solid Zn2SiO4 was re-fitted to be compatible with the new data in the willemite primary phase field. The thermodynamic data set agrees well with the recent experimental observations. It can be used for predicting, e.g., the thermodynamic properties and the domains of the phase diagram, like critical point of the liquid miscibility gap, with a better accuracy than using the previous assessments. A set of optimized model parameters were obtained, reproducing the reliable thermodynamic and phase equilibrium data within their experimental errors from 298 K to liquidus temperatures, over the entire composition range. The created database can be used in a Gibbs energy minimization software to calculate the thermodynamic properties and the phase diagram sections of interest.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Metallurgi och metalliska material (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Metallurgy and Metallic Materials (hsv//eng)
Nyckelord
- thermodynamic assessment
- ZnO-SiO2 system
- thermodynamic properties
- phase diagram
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
Hitta via bibliotek
Till lärosätets databas