Thin-Film Fuel Cells using a Sodium Silicate Binder with La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) and LaCePr Oxides (LCP) Membranes

Feng, ChuHubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China. (författare)

QC 20181218
Sodium silicate was used as a binder to prepare LaCePr oxides (LCP) and La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) thin films on a Ni0.8Co0.15Al0.05Li oxide ceramic substrate for the first time. The microstructure, morphology, and electrical properties of the LSCF-LCP thin films were characterized and investigated by using XRD, SEM, energy-dispersive X-ray spectroscopy, and electrochemical impedance spectroscopy. The film sintered at 600 degrees C presents promising density and has been successfully applied as the electrolyte membrane for solid-oxide fuel cells (SOFCs). Such a device achieved a respectable electrochemical performance with an open-circuit voltage of 1.04V and a maximum power output of 545mWcm(-2) at 575 degrees C. These findings suggest that sodium silicate is a suitable binder for the preparation of dense thin-film membranes for SOFCs. Moreover, the preparation technology based on sodium silicate eliminated degumming and high-temperature sintering, which resulted in greatly simplifying the preparation process of the thin-film fuel cell towards potential fuel cell commercialization.

Wang, BaoyuanKTH,Energiteknik,Hubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China(Swepub:kth)PI000000 (författare)
Zhu, JingHubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China. (författare)
Wang, HaoHubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China. (författare)
Zhu, BinKTH,Energiteknik,Hubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China(Swepub:kth)u1ybbo7e (författare)
Hubei Univ, Fac Phys & Elect Sci, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China.Energiteknik (creator_code:org_t)

Ingår i:Energy Technology: Wiley-VCH Verlagsgesellschaft6:2, s. 312-3172194-4288

Av författaren/redakt...: Feng, Chu; Wang, Baoyuan; Zhu, Jing; Wang, Hao; Zhu, Bin

Om ämnet

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