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Fast-charging effec...
Fast-charging effects on ageing for energy-optimized automotive LiNi1/3Mn1/3Co1/3O2/graphite prismatic lithium-ion cells
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- Mussa, Abdilbari (författare)
- KTH,Tillämpad elektrokemi,KTH Royal Inst Technol, Appl Electrochem, SE-10044 Stockholm, Sweden
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- Liivat, Anti (författare)
- Uppsala universitet,Strukturkemi
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- Marzano, Fernanda (författare)
- Uppsala universitet,Strukturkemi,Scania CV AB, SE-15187 Sodertalje, Sweden
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- Klett, Matilda (författare)
- KTH,Tillämpad elektrokemi,KTH Royal Inst Technol, Appl Electrochem, SE-10044 Stockholm, Sweden;Scania CV AB, SE-15187 Sodertalje, Sweden
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- Philippe, Bertrand, Dr. 1986- (författare)
- Uppsala universitet,Molekyl- och kondenserade materiens fysik
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- Tengstedt, Carl (författare)
- Scania CV AB, SE-15187 Sodertalje, Sweden.
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- Lindbergh, Göran, 1959- (författare)
- KTH,Tillämpad elektrokemi,KTH Royal Inst Technol, Appl Electrochem, SE-10044 Stockholm, Sweden
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- Edström, Kristina, Professor, 1958- (författare)
- Uppsala universitet,Strukturkemi
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- Lindström, Rakel Wreland, 1973- (författare)
- KTH,Tillämpad elektrokemi,KTH Royal Inst Technol, Appl Electrochem, SE-10044 Stockholm, Sweden
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- Svens, Pontus, 1970- (författare)
- KTH,Tillämpad elektrokemi,KTH Royal Inst Technol, Appl Electrochem, SE-10044 Stockholm, Sweden;Scania CV AB, SE-15187 Sodertalje, Sweden
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(creator_code:org_t)
- ELSEVIER SCIENCE BV, 2019
- 2019
- Engelska.
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Ingår i: Journal of Power Sources. - : ELSEVIER SCIENCE BV. - 0378-7753 .- 1873-2755. ; 422, s. 175-184
- Relaterad länk:
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https://doi.org/10.1...
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- The reactions in energy-optimized 25 Ah prismatic NMC/graphite lithium-ion cell, as a function of fast charging (1C-4C), are more complex than earlier described. There are no clear charging rate dependent trends but rather different mechanisms dominating at the different charging rates. Ageing processes are faster at 3 and 4C charging. Cycling with 3C-charging results in accelerated lithium plating but the 4C-charging results in extensive gas evolution that contribute significantly to the large cell impedance rise. Graphite exfoliation and accelerated lithium inventory loss point to the graphite electrode as the source of the gas evolution. The results are based on careful post-mortem analyses of electrodes using: scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and electrochemical impedance spectroscopy (EIS). SEM results show particle cracking independent of the charging rate used for the cycling. XPS and EIS generally indicate thicker surface film and larger impedance, respectively, towards the edge of the jellyrolls. For the intended application of a battery electric inner-city bus using this type of cell, charging rates of 3C and above are not feasible, considering battery lifetime. However, charging rates of 2C and below are too slow from the point of view of practical charging time.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Nyckelord
- Fast charging
- Lithium-ion battery
- Ageing
- Energy battery
- Electric vehicle
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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Till lärosätets databas
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Mussa, Abdilbari
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Liivat, Anti
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Marzano, Fernand ...
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Klett, Matilda
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Philippe, Bertra ...
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Tengstedt, Carl
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visa fler...
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Lindbergh, Göran ...
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Edström, Kristin ...
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Lindström, Rakel ...
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Svens, Pontus, 1 ...
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- Om ämnet
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- NATURVETENSKAP
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NATURVETENSKAP
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och Kemi
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- NATURVETENSKAP
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NATURVETENSKAP
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och Kemi
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och Materialkemi
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Journal of Power ...
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Kungliga Tekniska Högskolan
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Uppsala universitet