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Synthesis of Anemoc...
Synthesis of Anemoclemosides A and B, Two Saponins Isolated from Anemoclema glaucifolium
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- Bouillon, Marc E. (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Bertocco, Katia (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Bischoff, Laura (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Buri, Michelle (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Davies, Lucy R. (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Wilkinson, Elizabeth J. (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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- Lahmann, Martina (författare)
- Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales.
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Bangor Univ, Sch Chem, Deiniol Rd, Bangor LL57 2UW, Gwynedd, Wales (creator_code:org_t)
- 2020-11-11
- 2020
- Engelska.
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Ingår i: European Journal of Organic Chemistry. - : Wiley. - 1434-193X .- 1099-0690. ; 2020:48, s. 7470-7473
- Relaterad länk:
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https://research.ban...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Steroidal and triterpenoid saponins are attractive for their wide-ranging pharmacological properties. The triterpenoid saponins Anemoclemoside A and B are root constituents of the Chinese folk medicinal plant Anemoclema glaucifolium (Ranunculaceae). Both compounds feature an unusual cyclic acetal linkage to the carbohydrate l-arabinose in its open chain form rather than the typical glycosidic bond present in normal saponins. The straightforward and scalable syntheses of both saponins starting from l-arabinose as well as l-lyxose and l-rhamnose are described.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- Saponins
- Anemoclemosides
- Glycosylation
- Hederagenin glycosides
- Cyclic acetal glycosidic linkage
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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