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Preparation, charac...
Preparation, characterization and electrochemistry of an iron-only hydrogenase active site model covalently linked to a ruthenium tris(bipyridine) photosensitizer
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Cui, Hongguang (författare)
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Wang, Mei (författare)
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Duan, Lele (författare)
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- Sun, Licheng (författare)
- KTH,Organisk kemi
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(creator_code:org_t)
- 2008-06-19
- 2008
- Engelska.
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Ingår i: Journal of coordination chemistry (Print). - : Informa UK Limited. - 0095-8972 .- 1029-0389. ; 61:12, s. 1856-1861
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- An NH2-functionlized [Fe2S2] model complex of the iron-only hydrogenase active site was covalently linked to the tris( bipyridine) ruthenium photosensitizer. The [RuFeFe] trinuclear complex 1 was characterized by MS, IR, UV-vis, H-1 & C-13 NMR spectra. A quasi-reversible reduction peak at - 1.41V versus Ag/Ag+ for the (FeFeI)-Fe-I/(FeFe0)-Fe-I process is observed in the cyclic voltammogram of 1.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- diiron complex
- iron-only hydrogenase
- ruthenium photosensitizer
- trinuclear complex
- Chemistry
- Kemi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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