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Sökning: onr:"swepub:oai:DiVA.org:kth-343474" > Nanostructures of e...

  • Janewithayapun, Ratchawit,1998Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology (författare)

Nanostructures of etherified arabinoxylans and the effect of arabinose content on material properties

  • Artikel/kapitelEngelska2024

Förlag, utgivningsår, omfång ...

  • Elsevier BV,2024
  • printrdacarrier

Nummerbeteckningar

  • LIBRIS-ID:oai:DiVA.org:kth-343474
  • https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-343474URI
  • https://doi.org/10.1016/j.carbpol.2024.121846DOI
  • https://research.chalmers.se/publication/539868URI

Kompletterande språkuppgifter

  • Språk:engelska
  • Sammanfattning på:engelska

Ingår i deldatabas

Klassifikation

  • Ämneskategori:ref swepub-contenttype
  • Ämneskategori:art swepub-publicationtype

Anmärkningar

  • QC 20240318
  • To further our understanding of a thermoplastic arabinoxylan (AX) material obtained through an oxidation-reduction-etherification pathway, the role of the initial arabinose:xylose ratio on the material properties was investigated. Compression molded films with one molar substitution of butyl glycidyl ether (BGE) showed markedly different tensile behaviors. Films made from low arabinose AX were less ductile, while those made from high arabinose AX exhibited elastomer-like behaviors. X-ray scattering confirmed the presence of nanostructure formation resulting in nano-domains rich in either AX or BGE, from side chain grafting. The scattering data showed variations in the presence of ordered structures, nano-domain sizes and their temperature response between AX with different arabinose contents. In dynamic mechanical testing, three transitions were observed at approximately −90 °C, −50 °C and 80 °C, with a correlation between samples with more structured nano-domains and those with higher onset transition temperatures and lower storage modulus decrease. The mechanical properties of the final thermoplastic AX material can therefore be tuned by controlling the composition of the starting material.

Ämnesord och genrebeteckningar

Biuppslag (personer, institutioner, konferenser, titlar ...)

  • Hedenqvist, Mikael S.KTH,Polymera material,Wallenberg Wood Science Center,Kungliga Tekniska Högskolan (KTH),Royal Institute of Technology (KTH)(Swepub:kth)u10rkaxe (författare)
  • Cousin, FabriceLaboratoire Léon Brillouin, Université Paris-Saclay, UMR 12, CEA-CNRS, 91191 Gif Sur Yvette, France,Université Paris-Saclay,University Paris-Saclay (författare)
  • Idström, Alexander,1983Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)idstrom (författare)
  • Evenäs, Lars,1976Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; Wallenberg Wood Science Center, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)nlars (författare)
  • Lopez-Sanchez, Patricia,1977Department of Analytical Chemistry, Nutrition, and Food Science. Facultad de Ciencias, Instituto de Materiales (IMATUS), Universidade de Santiago de Compostela, Campus Terra, 27002, Lugo, Spain, Campus Terra,Universidade de Santiagode Compostela(Swepub:cth)patlop (författare)
  • Westman, Gunnar,1964Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; Wallenberg Wood Science Center, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)westman (författare)
  • Larsson, Anette,1966Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; Wallenberg Wood Science Center, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)anettel (författare)
  • Ström, Anna,1976Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)annastr (författare)
  • Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden; FibRe Center for Lignocellulose-based Thermoplastics, Chalmers University of Technology, SE-412 96 Gothenburg, SwedenChalmers tekniska högskola (creator_code:org_t)

Sammanhörande titlar

  • Ingår i:Carbohydrate Polymers: Elsevier BV3310144-86171879-1344

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