Formation of one-dimensional molybdenum oxide on Mo(112)

• The atomic structure of a reconstructed Mo(112)-O(2 x 3) surface has been revisited using photoelectron spectroscopy with synchrotron radiation, scanning tunneling microscopy, infrared reflection absorption spectroscopy and density functional theory. In contrast to previous models, the results are rationalized in terms of the formation of one-dimensional, Mo=O terminated molybdenum oxide involving corner sharing distorted [MoO(6)] octahedra on the (1 x 3) reconstructed Mo(112) surface.

Ämnesord

NATURVETENSKAP  -- Fysik -- Annan fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Other Physics Topics (hsv//eng)

Nyckelord

Molybdenum oxides

Surface reconstruction

Infrared spectroscopy

Photoelectron spectroscopy

Density functional theory

Publikations- och innehållstyp

ref (ämneskategori)

art (ämneskategori)