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pi-Extended perylen...
pi-Extended perylene diimide double-heterohelicenes as ambipolar organic semiconductors for broadband circularly polarized light detection
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- Zhang, Li (författare)
- Xiamen Univ, Peoples R China
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- Song, Inho (författare)
- Seoul Natl Univ, South Korea
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- Ahn, Jaeyong (författare)
- Seoul Natl Univ, South Korea
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- Han, Myeonggeun (författare)
- Pohang Univ Sci & Technol POSTECH, South Korea
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- Linares, Mathieu (författare)
- Linköpings universitet,Bioinformatik,Tekniska fakulteten
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- Surin, Mathieu (författare)
- Univ Mons UMONS, Belgium
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- Zhang, Hui-Jun (författare)
- Xiamen Univ, Peoples R China
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- Oh, Joon Hak (författare)
- Seoul Natl Univ, South Korea
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- Lin, Jianbin (författare)
- Xiamen Univ, Peoples R China
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(creator_code:org_t)
- 2021-01-08
- 2021
- Engelska.
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Ingår i: Nature Communications. - : Nature Research. - 2041-1723. ; 12:1
- Relaterad länk:
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https://liu.diva-por... (primary) (Raw object)
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https://www.nature.c...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Despite great challenges, the development of new molecular structures with multiple and even conflicting characteristics are eagerly pursued for exploring advanced applications. To develop high-performance chiral organic semiconducting molecules, a distorted -system is required for strong coupling with circularly polarized light (CPL), whereas planar pi -stacking systems are necessary for high charge-carrier mobility. To address this dilemma, in this work, we introduce a skeleton merging approach through distortion of a perylene diimide (PDI) core with four fused heteroaromatics to form an ortho-pi -extended PDI double-[7]heterohelicene. PDI double helicene inherits a high dissymmetry factor from the helicene skeleton, and the extended pi -planar system concurrently maintains a high level of charge transport properties. In addition, ortho-pi -extension of the PDI skeleton brings about near-infrared (NIR) light absorption and ambipolar charge transport abilities, endowing the corresponding organic phototransistors with high photoresponsivity of 450 and 120mAW(-1) in p- and n-type modes respectively, along with a high external quantum efficiency (89%) under NIR light irradiations. Remarkably, these multiple characteristics enable high-performance broadband CPL detections up to NIR spectral region with chiral organic semiconductors. In organic semiconducting molecules materials, distorted pi -systems enable strong coupling with circular polarized light while planar pi -stacking systems are necessary for high charge-carrier mobility. Here, the authors address this dilemma by introducing a skeleton merging approach through distortion of a perylene diimide core with four fused heteroaromatics to form a pi -extended double helicene.
Ämnesord
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
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