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Nanostructure and f...
Nanostructure and functional group engineering of black phosphorus via plasma treatment for CO2 photoreduction
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- Zhu, Xingwang (författare)
- Jiangsu Univ, Peoples R China
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- Zhou, Guli (författare)
- Jiangsu Univ, Peoples R China
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- Wang, Zhaolong (författare)
- Jiangsu Univ, Peoples R China
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- Zhong, Kang (författare)
- Jiangsu Univ, Peoples R China
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- Ding, Penghui (författare)
- Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten
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- Song, Yanhua (författare)
- Jiangsu Univ Sci & Technol, Peoples R China
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- Yuan, Junjie (författare)
- Jiangsu Univ, Peoples R China
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- She, Yuanbin (författare)
- Zhejiang Univ Technol, Peoples R China
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- Li, Huaming (författare)
- Jiangsu Univ, Peoples R China
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- Xu, Hui (författare)
- Jiangsu Univ, Peoples R China
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(creator_code:org_t)
- ELSEVIER SCI LTD, 2021
- 2021
- Engelska.
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Ingår i: Journal of CO2 Utilization. - : ELSEVIER SCI LTD. - 2212-9820 .- 2212-9839. ; 54
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- As an emerging two-dimensional (2D) semiconductor, black phosphorus (BP) has attracted great interest in photocatalytic CO2 reduction, but the performance is restricted by the low surface reactivity and poor stability. Exfoliating BP into the 2D structure is an effective method to increase the exposure of active sites. However, the intrinsic surface reactivity and stability cannot be improved, and, the widely used liquid-phase exfoliation method is time-consuming and laborious. In this work, we successfully exfoliates the bulk BP into ultrathin BP nanosheets with dense surface amino-functional groups (BP-NH2) using NH3 plasma treatment. The 2D structure can shorten the photo-excited charges migration distance and improve the exposure of surface-active sites. Furthermore, the amino-functional groups on ultrathin BP nanosheets can prevent the destruction of BP nanosheets in ambient air, favoring the charge separation, CO2 adsorption and activation during the catalytic process. Benefiting from integrated advantages of amino functional groups, the optimal BP-NH2 exhibits a photocatalytic CO2 reduction rate to CO of 27.6 mu mol g(-1) h(-1) with a selectivity of 87.0 %, both of which are higher than those of pristine bulk BP. This work presents ideas for stabilizing BP and improving the CO2 reduction performance simultaneously.
Ämnesord
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
Nyckelord
- CO2 reduction; Black phosphorus; Amino; Photocatalyst
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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Till lärosätets databas
- Av författaren/redakt...
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Zhu, Xingwang
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Zhou, Guli
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Wang, Zhaolong
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Zhong, Kang
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Ding, Penghui
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Song, Yanhua
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Yuan, Junjie
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She, Yuanbin
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Li, Huaming
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Xu, Hui
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- Om ämnet
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- NATURVETENSKAP
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NATURVETENSKAP
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och Kemi
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och Annan kemi
- Artiklar i publikationen
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Journal of CO2 U ...
- Av lärosätet
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Linköpings universitet