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Rapid solidificatio...
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Zhang, BenSoochow Univ, Peoples R China
(författare)
Rapid solidification for green-solvent-processed large-area organic solar modules with >16% efficiency
- Artikel/kapitelEngelska2024
Förlag, utgivningsår, omfång ...
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2024
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ROYAL SOC CHEMISTRY,2024
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LIBRIS-ID:oai:DiVA.org:liu-202503
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-202503URI
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https://doi.org/10.1039/d4ee00680aDOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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Funding Agencies|Priority Academic Program Development of Jiangsu Higher Education Institutions [52325307, 52273188, 22075194, 22309129]; National Natural Science Foundation of China [20KJA430010]; Natural Science Foundation of the Jiangsu Higher Education Institutions of China; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); Collaborative Innovation Center of Suzhou Nano Science and Technology [2023NSFSC0990]; Key Laboratory of Polymeric Materials Design and Synthesis for Biomedical Function, Soochow University, Sichuan Science and Technology Program [DE-AC02-05CH11231]; Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy; Shanghai Synchrotron Radiation Facility (SSRF)
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Enabling green-solvent-processed large-area organic solar cells (OSCs) is of great significance to their industrialization. However, precisely controlling the temperature-dependent fluid mechanics and evaporation behavior of green solvents with high-boiling points is challenging. Controlling these parameters is essential to prevent the non-uniform distribution of active layer components and severe molecule aggregation, which collectively degrade the power conversion efficiency (PCE) of large-scale devices. In this study, we revealed that the temperature gradient distribution across a wet film is the root of the notorious Marangoni effect, which leads to the formation of a severely non-uniform active layer on a large scale. Thus, a rapid solidification strategy was proposed to accelerate the evaporation of toluene, a green solvent, at room temperature. This strategy simultaneously inhibits the Marangoni effect and suppresses molecular aggregation in the wet film, allowing the formation of a nano-scale phase separation active layer with uniform morphology. The resultant toluene-processed 15.64-cm2 large-area OSC module achieves an outstanding PCE of 16.03% (certified: 15.69%), which represents the highest reported PCE of green-solvent-processed OSC modules. Notably, this strategy also exhibits a weak scale dependence on the PCE, and we successfully achieved a state-of-the-art PCE of 14.45% for a 72.00-cm2 OSC module. A rapid solidification strategy was developed for simultaneously avoiding the Marangoni effect and suppressing molecular aggregation. The resultant 15.64 cm2 large-area OSC module exhibited a record power conversion efficiency of 16.03%.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Chen, WeijieSoochow Univ, Peoples R China
(författare)
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Chen, HaiyangSoochow Univ, Peoples R China
(författare)
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Zeng, GuangSoochow Univ, Peoples R China
(författare)
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Zhang, RuiLinköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten(Swepub:liu)ruizh84
(författare)
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Li, HongxiangSichuan Univ, Peoples R China
(författare)
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Wang, YunfeiUniv Southern Mississippi, MS 39406 USA
(författare)
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Gu, XiaodanUniv Southern Mississippi, MS 39406 USA
(författare)
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Sun, WeiweiSoochow Univ, Peoples R China
(författare)
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Gu, HaoSoochow Univ, Peoples R China
(författare)
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Gao, FengLinköpings universitet,Elektroniska och fotoniska material,Tekniska fakulteten(Swepub:liu)fenga88
(författare)
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Li, YaowenSoochow Univ, Peoples R China
(författare)
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Li, YongfangSoochow Univ, Peoples R China; Chinese Acad Sci, Peoples R China
(författare)
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Soochow Univ, Peoples R ChinaElektroniska och fotoniska material
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Energy & Environmental Science: ROYAL SOC CHEMISTRY1754-56921754-5706
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Zhang, Ben
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Chen, Weijie
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Chen, Haiyang
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Zeng, Guang
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Zhang, Rui
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Li, Hongxiang
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visa fler...
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Wang, Yunfei
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Gu, Xiaodan
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Sun, Weiwei
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Gu, Hao
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Gao, Feng
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Li, Yaowen
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Li, Yongfang
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