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Reversible phase tr...
Reversible phase transition in Zn₂(O,O-di(cyclohexyl)dithiophosphate)₄, studied by Raman spectroscopy and compared with NMR results
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Lidström-Larsson, Margareta (författare)
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- Holmgren, Allan (författare)
- Luleå tekniska universitet,Industriell miljö- och processteknik
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(creator_code:org_t)
- Elsevier BV, 2004
- 2004
- Engelska.
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Ingår i: Vibrational Spectroscopy. - : Elsevier BV. - 0924-2031 .- 1873-3697. ; 34:2, s. 243-246
- Relaterad länk:
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https://urn.kb.se/re...
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visa fler...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- It was recently shown by solid state ³¹P NMR spectroscopy that the number of phosphorous signals from the complex Zn₂(O,O-di(cyclohexyl)DTP)₄ varied reversibly with the temperature. According to the present study, Raman spectra of the same metal complex were also temperature dependent. Spectral features affected by the temperature changed reversibly upon raising and lowering the temperature. It was shown that conformational change of the hexyl rings and the P---O---C entities occurred in the temperature range between 40 and 55°C.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Metallurgi och metalliska material (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Metallurgy and Metallic Materials (hsv//eng)
Nyckelord
- Chemistry of Interfaces
- Gränsytors kemi
- Process Metallurgy
- Processmetallurgi
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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