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Physicochemical and tribological properties of gemini-type halogen-free dicationic ionic liquids

Yu, Qiangliang (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China. Lubricating Oil Key Laboratory of Petro China, Lanzhou Lubricating Oil Research & Development Institute of Petro China, Lanzhou, China
Zhang, Chaoyang (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Dong, Rui (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, China
visa fler...
Shi, Yijun (författare)
Luleå tekniska universitet,Maskinelement
Wang, Yurong (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, China
Bai, Yanyan (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, China
Zhang, Jiaying (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, China
Cai, Meirong (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Zhou, Feng (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
Liu, Weimin (författare)
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
visa färre...
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China Lubricating Oil Key Laboratory of Petro China, Lanzhou Lubricating Oil Research & Development Institute of Petro China, Lanzhou, China State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China (creator_code:org_t)
2020-07-15
2021
Engelska.
Ingår i: Friction. - : Springer. - 2223-7690 .- 2223-7704. ; 9:2, s. 344-355
  • Tidskriftsartikel (refereegranskat)
Abstract Ämnesord
Stäng  
  • A series of new halogen-free dicationic ionic liquids (ILs) with different alkyl chain lengths were prepared, and the relationship between the alkyl chain length, physicochemical and tribological properties of ILs, and their role as neat lubricant for steel-steel friction pairs, was investigated. Evaluation of stability during hydrolysis and copper strip corrosion test results show that synthetic ILs are stable and not corrosive to metal contacts, due to the halogen-free anions. The friction and wear test results indicate that ILs with long alkyl chains have excellent friction-reducing and anti-wear properties, especially at high temperatures. Based on the surface three-dimensional (3D) profiles, electrical contact resistance, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and the X-ray photoelectron spectrometry (XPS) analysis of the worn surfaces of steel discs, we can conclude that the efficiency of ILs is due to the formation of high quality tribofilms that consist of both tribochemical reaction and ordered absorption films.

Ämnesord

TEKNIK OCH TEKNOLOGIER  -- Maskinteknik -- Tribologi (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Mechanical Engineering -- Tribology (hsv//eng)

Nyckelord

halogen-free
dicationic ionic liquids (ILs)
lubricant
tribofilm
Machine Elements
Maskinelement

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