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Sökning: onr:"swepub:oai:DiVA.org:ltu-90488" > The beauty of being...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00006047naa a2200637 4500
001oai:DiVA.org:ltu-90488
003SwePub
008220502s2022 | |||||||||||000 ||eng|
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0247 a https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-904882 URI
0247 a https://doi.org/10.1016/j.jcat.2022.04.0292 DOI
0247 a https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-1948342 URI
0247 a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4777622 URI
040 a (SwePub)ltud (SwePub)umud (SwePub)uu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
1001 a Khasevani, Sepideh G.u Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)sepgho
2451 0a The beauty of being complex: Prussian blue analogues as selective catalysts and photocatalysts in the degradation of ciprofloxacin
264 1b Elsevier,c 2022
338 a print2 rdacarrier
500 a Validerad;2022;Nivå 2;2022-05-11 (sofila)
520 a We investigate the performance of four Prussian blue analogues (PBAs) as catalysts for the selective degradation of ciprofloxacin in water, under both dark and illumination conditions. We show that no light is actually needed to induce a selective degradation of the molecular target, while light irradiation spurs the process, without, however, resulting in the commonly reported photolysis-supported breaking down. We present a systematic characterization of the PBAs aiming at interpreting the catalytic outcomes in the light of a classic coordination chemistry analysis, empowered by the most recent findings in literature. We show that varying the transition metal binding the N atom of the cyanide bridge is key to promote photoinduced charge generation and transfer, which effectively disrupts the molecular target. The analysis of the materials before and after the irradiation with solar simulated light results in a change of the lattice parameters, indicating the possibility of a light-induced spin cross-over.
650 7a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng
650 7a NATURVETENSKAPx Kemix Fysikalisk kemi0 (SwePub)104022 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Physical Chemistry0 (SwePub)104022 hsv//eng
650 7a NATURVETENSKAPx Biologix Biofysik0 (SwePub)106032 hsv//swe
650 7a NATURAL SCIENCESx Biological Sciencesx Biophysics0 (SwePub)106032 hsv//eng
653 a Prussian blue analogues
653 a Ciprofloxacin degradation
653 a Photocatalysis
653 a Auto-catalytic reactions
653 a Mössbauer spectroscopy
653 a Engineering Materials
653 a Materialteknik
653 a Experimentell fysik
653 a Experimental Physics
7001 a Nikjoo, Dariush,d 1977-u Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)darnik
7001 a Ojwang, Dickson O.,d 1985-u Uppsala universitet,Strukturkemi4 aut0 (Swepub:uu)dicoj366
7001 a Nodari, Lucau Dipartimento di Scienze Chimiche, Università degli Studi di Padova, 35131 Padova, Italy; Istituto di Chimica della Materia Condensata e di Tecnologie per l’Energia, ICMATE-CNR, 35127 Padova, Italy,Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy.;Ist Chim Mat Condensata & Tecnol Energia ICMATE-CN, Padua I-35127, Italy.4 aut
7001 a Sarmad, Shokatu Umeå universitet,Kemiska institutionen,Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, SE-90871 Umeå, Sweden,Umeå Univ, Chem Biol Ctr, Dept Chem, Tech Chem, SE-90871 Umeå, Sweden.4 aut0 (Swepub:umu)shsa0039
7001 a Mikkola, Jyri-Pekkau Umeå universitet,Kemiska institutionen,Technical Chemistry, Department of Chemistry, Chemical-Biological Centre, Umeå University, SE-90871 Umeå, Sweden; Industrial Chemistry & Reaction Engineering, John Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, Fl-20500 Åbo-Turku, Finland,Umeå Univ, Chem Biol Ctr, Dept Chem, Tech Chem, SE-90871 Umeå, Sweden.;Abo Akad Univ, John Gadolin Proc Chem Ctr, Ind Chem & React Engn, Biskopsgatan 8, FI-20500 Abo Turku, Finland.4 aut0 (Swepub:umu)jymi0001
7001 a Rigoni, Federicau Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, 30170 Venezia-Mestre, Italy,Foscari Univ Venice, Dept Mol Sci & Nanosyst, I-30170 Venice, Italy.4 aut
7001 a Concina, Isabellau Luleå tekniska universitet,Materialvetenskap,Luleå University of Technology, Department of Engineering Sciences and Mathematics, Luleå, Sweden,Luleå Univ Technol, Dept Engn Sci & Math, S-98187 Luleå, Sweden.;Luleå Univ Technol, Dept Engn Sci & Math, Div Mat Sci, S-98187 Luleå, Sweden.4 aut0 (Swepub:ltu)isacon
7102 a Luleå tekniska universitetb Materialvetenskap4 org
7730 t Journal of Catalysisd : Elsevierg 410, s. 307-319q 410<307-319x 0021-9517x 1090-2694
8564 u https://doi.org/10.1016/j.jcat.2022.04.029y Fulltext
8564 u https://umu.diva-portal.org/smash/get/diva2:1662792/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print
8564 u https://uu.diva-portal.org/smash/get/diva2:1673049/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-90488
8564 8u https://doi.org/10.1016/j.jcat.2022.04.029
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-194834
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-477762

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