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Phase behavior in t...
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Mele, StefaniaDept. Scienze Chimiche e Geologiche, University of Cagliari, Cittadella Universitaria Monserrato, S.S. 554 Bivio per Sestu, 09042 Monserrato, CA, Italy; PANalytical S.r.l, Spectra PLC, Via Cadore 21, 20851 Lissone, MB, Italy
(författare)
Phase behavior in the biologically important oleic acid/sodium oleate/water system
- Artikel/kapitelEngelska2018
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Elsevier,2018
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LIBRIS-ID:oai:DiVA.org:mau-4317
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https://urn.kb.se/resolve?urn=urn:nbn:se:mau:diva-4317URI
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https://doi.org/10.1016/j.chemphyslip.2017.11.017DOI
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https://lup.lub.lu.se/record/497e6a6c-c94c-45de-8fcd-bc5ec989b10dURI
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Språk:engelska
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Sammanfattning på:engelska
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The phase behavior in the oleic acid/sodium oleate/normal saline (0.15M NaCl aqueous solution) system has been determined. For this purpose visual inspection of samples between crossed polarizers, and Small Angle X-ray diffraction was used to identify the various phases and their unit cell dimensions. A rich phase behavior was observed for the ternary system, featuring reverse micellar, micellar cubic, hexagonal, and cubic phases, and large regions with lamellar phases. As expected the ratio the 'oleic acid/sodium oleate' determines the pH and as a consequence the phase behavior. The results could be modeled by an extended Henderson-Hasselbalch (HH) equation, which takes into account the electrostatic potential at the aqueous lipid interface. The knowledge obtained is important for understanding the lipolysis of triglycerides, as the phase behavior of the end-product of the reaction regulates how well the insoluble product can be dispersed and consequently the kinetics of the process.
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Söderman, OlleLund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)fk1-oso
(författare)
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Ljusberg-Wahrén, HelenaLund University,Lunds universitet,LU Innovation,Sektionen Forskning, samverkan och innovation,Universitetsförvaltningen,Universitetets ledning och förvaltning,Research, Collaboration and Innovation,Central Administration,University Management and Central Administration(Swepub:lu)livs-hlj
(författare)
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Thuresson, KristerMalmö University,Malmö universitet,Institutionen för biomedicinsk vetenskap (BMV),Delta of Sweden, Box 801, SE-301 18 Halmstad, Sweden(Swepub:lu)fk1-kth
(författare)
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Monduzzi, MauraDept. Scienze Chimiche e Geologiche, University of Cagliari, Cittadella Universitaria Monserrato, S.S. 554 Bivio per Sestu, 09042 Monserrato, CA, Italy
(författare)
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Nylander, TommyLund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)fk1-tny
(författare)
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Dept. Scienze Chimiche e Geologiche, University of Cagliari, Cittadella Universitaria Monserrato, S.S. 554 Bivio per Sestu, 09042 Monserrato, CA, Italy; PANalytical S.r.l, Spectra PLC, Via Cadore 21, 20851 Lissone, MB, ItalyFysikalisk kemi
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Chemistry and Physics of Lipids: Elsevier211, s. 30-360009-30841873-2941
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