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Selective Palladium...
Selective Palladium-Catalyzed Allenic C-H Bond Oxidation for the Synthesis of [3]Dendralenes
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- Qiu, Youai (författare)
- Stockholms universitet,Institutionen för organisk kemi
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- Posevins, Daniels (författare)
- Stockholms universitet,Institutionen för organisk kemi
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- Bäckvall, Jan-E. (författare)
- Stockholms universitet,Institutionen för organisk kemi
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(creator_code:org_t)
- 2017-09-07
- 2017
- Engelska.
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Ingår i: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 56:42, s. 13112-13116
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Abstract
Ämnesord
Stäng
- A highly selective palladium-catalyzed allenic C-H bond oxidation was developed, and it provides a novel and straightforward synthesis of [3]dendralene derivatives. A variety of [3]dendralenes with diverse substitution patterns are accessible with good efficiency and high stereoselectivity. The reaction tolerates a broad substrate scope containing various functional groups on the allene moiety, including ketone, aldehyde, ester, and phenyl groups. Also, a wide range of olefins with both electron-donating and electron-withdrawing aryls, acrylate, sulfone, and phosphonate groups are tolerated.
Ämnesord
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- dendralenes
- allenes
- olefination
- palladium
- regioselectivity
- organisk kemi
- Organic Chemistry
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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