Sökning: onr:"swepub:oai:DiVA.org:su-195958" > The reactivity of m...
Fältnamn | Indikatorer | Metadata |
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000 | 02730naa a2200517 4500 | |
001 | oai:DiVA.org:su-195958 | |
003 | SwePub | |
008 | 210830s2021 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-1959582 URI |
024 | 7 | a https://doi.org/10.1016/j.cplett.2021.1386772 DOI |
040 | a (SwePub)su | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Sundelin, Davidu Stockholms universitet,Fysikum4 aut0 (Swepub:su)dasu1491 |
245 | 1 0 | a The reactivity of methanimine radical cation (H2CNH•+) and its isomer aminomethylene (HCNH2•+) with C2H4 |
264 | 1 | b Elsevier BV,c 2021 |
338 | a print2 rdacarrier | |
520 | a Experimental and theoretical studies are presented on the reactivity of H2CNH'+ (methanimine) and HCNH2'+ (aminomethylene) with ethene (C2H4). Selective isomer generation is performed via dissociative photoionization of suitable neutral precursors and reactive cross sections and branching ratios are measured as a function of photon and collision energies. Differences between isomers' reactivity are discussed in light of ab-initio calculations on reaction mechanisms. The main products, for both isomers, are H-elimination, most likely occurring from covalently bound adducts (giving c-CH2CH2CHNH+/CH2NHCHCH2+) and H' atom transfer to yield H2CNH2+. The astrochemical implications of the results are briefly addressed. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
650 | 7 | a NATURVETENSKAPx Fysik0 (SwePub)1032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciences0 (SwePub)1032 hsv//eng |
653 | a Interstellar medium | |
653 | a Rate constant | |
653 | a Astrochemistry molecular astrophysics | |
653 | a Isomerism | |
653 | a Protonated ketenimine | |
653 | a Ion-molecule reactions | |
653 | a Titan's atmosphere | |
700 | 1 | a Ascenzi, D.4 aut |
700 | 1 | a Richardson, V.4 aut |
700 | 1 | a Alcaraz, C.4 aut |
700 | 1 | a Polášek, M.4 aut |
700 | 1 | a Romanzin, C.4 aut |
700 | 1 | a Thissen, R.4 aut |
700 | 1 | a Tosi, P.4 aut |
700 | 1 | a Žabka, J.4 aut |
700 | 1 | a Geppert, Wolfu Stockholms universitet,Fysikum4 aut0 (Swepub:su)wgeppert |
710 | 2 | a Stockholms universitetb Fysikum4 org |
773 | 0 | t Chemical Physics Lettersd : Elsevier BVg 777q 777x 0009-2614x 1873-4448 |
856 | 4 | u https://arxiv.org/abs/2111.01703y arXiv:2111.01703 |
856 | 4 | u http://arxiv.org/pdf/2111.01703 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-195958 |
856 | 4 8 | u https://doi.org/10.1016/j.cplett.2021.138677 |
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