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Synthesis and struc...
Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe-2(mμ-SCHR2)(2)(NO)(4)], R = Me, Ph
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- Davidovich, P. B. (författare)
- Russia
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- Gurzhiy, V. V. (författare)
- Russia
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- Sabina, N. A. (författare)
- Russia
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- Shchukarev, Andrey (författare)
- Umeå universitet,Kemiska institutionen
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- Garabadzhiu, A. V. (författare)
- Russia
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- Belyaev, A. N. (författare)
- Russia
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(creator_code:org_t)
- Elsevier, 2015
- 2015
- Engelska.
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Ingår i: Polyhedron. - : Elsevier. - 0277-5387 .- 1873-3719. ; 90, s. 197-201
- Relaterad länk:
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https://dspace.spbu....
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- New dinitrosyl iron complexes of binuclear structure [Fe-2(mu-SCHMe2)(2)(NO)(4)] and [Fe-2(mu-SCHPh2)(2)(NO)(4)] were first synthesized employing new method from Fe(CO)(5), corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Crystal structure
- Thiolate ligands
- Dinitrosyl iron complex
- Nitric oxide donor
- DFT calculations
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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