Sökning: onr:"swepub:oai:DiVA.org:umu-112728" > Electron transport ...
Fältnamn | Indikatorer | Metadata |
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000 | 02841naa a2200325 4500 | |
001 | oai:DiVA.org:umu-112728 | |
003 | SwePub | |
008 | 151214s1992 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-1127282 URI |
024 | 7 | a https://doi.org/10.1016/0022-0728(92)80275-92 DOI |
040 | a (SwePub)umu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Larsson, Henriku Umeå universitet,Kemiska institutionen4 aut0 (Swepub:umu)hela0002 |
245 | 1 0 | a Electron transport in quaternized poly(4-vinylpyridine) films containing pentacyanoferrate(II/III) on electrodes. The influence of the binding type of the electroactive complex |
264 | 1 | b Elsevier,c 1992 |
338 | a print2 rdacarrier | |
520 | a This study is an attempt to investigate how charge transport in thin redox polymer films spin-coated onto glassy carbon electrode surfaces is affected by the way in which the electroactive group is bound to the polymeric matrix. Two different redox polymers based on methylated and cross-linked poly(4-vinylpyridine) and pentacyanoferrate(II/III) have been synthesized. In the first case, an anionic complex formed by coordinating pyridine to pentacyanoferrate(II) was electrostatically bound to the methylated pyridine groups in the polymer matrix. In the other case, pentacyanoferroate(II) was coordinated directly to unmethylated pyridine groups in the partly methylated polymer film. The film thicknesses were estimated with ellipsometric measurements. Their electrochemical characteristics were investigated using cyclic voltammetry, chronocoulometry and impedance spectroscopy. The apparent charge-transport diffusion coefficient D(app) was almost two orders of magnitude greater in the ion-exchange polymer than in the redox polymer with coordinatively bound electroactive groups. The temperature dependence of D(app) was evaluated using Arrhenius plots. | |
650 | 7 | a NATURVETENSKAPx Kemix Analytisk kemi0 (SwePub)104012 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Analytical Chemistry0 (SwePub)104012 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Fysikalisk kemi0 (SwePub)104022 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Physical Chemistry0 (SwePub)104022 hsv//eng |
700 | 1 | a Lindholm, Brittau Umeå universitet,Kemiska institutionen4 aut |
700 | 1 | a Sharp, Michaelu Umeå universitet,Kemiska institutionen4 aut0 (Swepub:umu)mish0001 |
710 | 2 | a Umeå universitetb Kemiska institutionen4 org |
773 | 0 | t Journal of Electroanalytical Chemistryd : Elsevierg 336:1-2, s. 263-279q 336:1-2<263-279x 0022-0728x 1873-2569x 1572-6657 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-112728 |
856 | 4 8 | u https://doi.org/10.1016/0022-0728(92)80275-9 |
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