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Three dimensional s...
Three dimensional star-like mesoporous nitrogen-doped carbon anchored with highly dispersed Fe and Ce dual-sites for efficient oxygen reduction reaction in Zn-air battery
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- Bi, Zenghui (författare)
- School of Electronic Communication Technology, Shenzhen Institute of Information Technology, Shenzhen, China; Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Materials and Energy, Yunnan University, Kunming, China
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- Wang, Yuwen (författare)
- Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Materials and Energy, Yunnan University, Kunming, China
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- Chen, Jianbing (författare)
- Research Academy of Non-metallic Mining Industry Development, Materials and Environmental Engineering College, Chizhou University, Chizhou, China
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- Zhang, Xianxi (författare)
- School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, China
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- Zhou, Shuxing (författare)
- Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang, China
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- Wang, Xinzhong (författare)
- School of Electronic Communication Technology, Shenzhen Institute of Information Technology, Shenzhen, China
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- Wågberg, Thomas, 1971- (författare)
- Umeå universitet,Institutionen för fysik
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- Hu, Guangzhi (författare)
- Umeå universitet,Institutionen för fysik,Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Materials and Energy, Yunnan University, Kunming, China
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(creator_code:org_t)
- Elsevier, 2022
- 2022
- Engelska.
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Ingår i: Colloid and Interface Science Communications. - : Elsevier. - 2215-0382. ; 49
- Relaterad länk:
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https://doi.org/10.1...
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https://umu.diva-por... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Metal‑nitrogen‑carbon materials (M-N-C) have attracted much attention due to their low cost, high abundance, and efficient catalytic performance. Nevertheless, Fe-N-C materials are considered the most promising oxygen reduction reaction (ORR) catalysts for replacing noble metals. Ce is chemically active and has many metal valence states, and empty orbitals that can participate in coordination. On this basis, Fe, Ce-codoped catalyst was constructed in this study. The synergistic effect of the dual metal centers was verified, and a Fe, Ce-codoped nitrogen-doped carbon (FeCeNC) with six equal branch angles was proposed. The half-wave potential for the ORR catalyzed by FeCeNC is 0.855 V. As a rechargeable Zn-air battery cathode catalyst, FeCeNC exhibits excellent electrochemical performances, with an open-circuit voltage of 1.427 V, a maximum power density of 169.2 mW cm−2 and a stable cycling time of 80 h, demonstrating an excellent cycle performance.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- Fe
- Ce-codoped
- Metal‑nitrogen‑carbon
- Oxygen reduction reaction
- Zinc-air battery
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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