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Thermal conductivit...
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Andersson, OveUmeå universitet,Institutionen för fysik
(författare)
Thermal conductivity of normal and deuterated tetrahydrofuran clathrate hydrates
- Artikel/kapitelEngelska1996
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Elsevier,1996
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LIBRIS-ID:oai:DiVA.org:umu-223701
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https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-223701URI
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https://doi.org/10.1016/0022-3697(95)00157-3DOI
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Språk:engelska
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Sammanfattning på:engelska
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The thermal conductivity λ of normal and deuterated tetrahydrofuran (THF) clathrate hydrates has been measured at temperatures in the range 55-250 K and at pressures up to 0.16 GPa. The normal and deuterated samples exhibited the same values of λ to within 5%. At isobaric heating, the transition from the proton ordered low temperature (LT) phase to the proton disordered high temperature (HT) phase was detected as a discontinuous decrease of λ by about 15% for both the normal and the deuterated samples. The magnitude is nearly the same as that found previously for the related transition phase XI → phase Ih of ice and might be due to a change in the lattice anharmonicity. The thermal conductivity of the LT and HT phases increased slightly with increasing temperature and, hence, these crystalline phases exhibited both a glass-like λ(T). These results can be described using the resonance scattering model in which the phonons are scattered against THF vibrations. The LT phase of both samples exhibited a slight increase of λ with increasing pressure whereas that of the HT phases was roughly independent of pressure, showing that λ does not depend on density.
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Suga, H.Umeå universitet,Institutionen för fysik
(författare)
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Umeå universitetInstitutionen för fysik
(creator_code:org_t)
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Ingår i:Journal of Physics and Chemistry of Solids: Elsevier57:1, s. 125-1320022-36971879-2553
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