Sökning: onr:"swepub:oai:DiVA.org:umu-57664" > Effect of ion adsor...
Fältnamn | Indikatorer | Metadata |
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000 | 02420naa a2200397 4500 | |
001 | oai:DiVA.org:umu-57664 | |
003 | SwePub | |
008 | 120808s2012 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-576642 URI |
024 | 7 | a https://doi.org/10.1002/jssc.2012001382 DOI |
040 | a (SwePub)umu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Chen, Xiao-Jia4 aut |
245 | 1 0 | a Effect of ion adsorption on CEC separation of small molecules using hypercrosslinked porous polymer monolithic capillary columns |
264 | c 2012-06-28 | |
264 | 1 | b Wiley-VCH Verlagsgesellschaft,c 2012 |
338 | a print2 rdacarrier | |
520 | a Both poly(styrene-co-vinylbenzyl chloride-co-divinylbenzene) and poly(4-methylstyrene-co-vinylbenzyl chloride-co-divinylbenzene) monolithic columns have been hypercrosslinked and for the first time used to achieve capillary electrochromatographic separations. Although these columns do not contain ionizable functionalities, electroosmotic flow was observed due to adsorption of ions from a buffer solution contained in the mobile phase on the surface of the hydrophobic polymer. An increase of more than one order of magnitude was observed with the use of both monolithic polymers. The hypercrosslinking reaction creates a large surface area thus enabling adsorption of a much larger number of ions. Alkylbenzenes were successfully separated using the hypercrosslinked monolithic columns. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
653 | a Capillary electrochromatography | |
653 | a Hypercrosslinking | |
653 | a Ion adsorption | |
653 | a Polymer monolith | |
700 | 1 | a Dinh, Ngoc Phuoc,d 1985-u Umeå universitet,Kemiska institutionen,Merck SeQuant AB, Umeå, Sweden4 aut0 (Swepub:umu)ding0003 |
700 | 1 | a Zhao, Jing4 aut |
700 | 1 | a Wang, Yi-Tao4 aut |
700 | 1 | a Li, Shao-Ping4 aut |
700 | 1 | a Svec, Frantisek4 aut |
710 | 2 | a Umeå universitetb Kemiska institutionen4 org |
773 | 0 | t Journal of Separation Scienced : Wiley-VCH Verlagsgesellschaftg 35:12, s. 1502-1505q 35:12<1502-1505x 1615-9306x 1615-9314 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-57664 |
856 | 4 8 | u https://doi.org/10.1002/jssc.201200138 |
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