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Towards optimal sel...
Towards optimal selective fractionation for Nordic woody biomass using novel amine–organic superbase derived switchable ionic liquids (SILs)
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Anugwom, Ikenna (författare)
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Eta, Valerie (författare)
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Virtanen, Pasi (författare)
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Mäki-Arvela, Paivi (författare)
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- Hedenström, Mattias (författare)
- Umeå universitet,Kemiska institutionen,CLIC
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Yibo, Ma (författare)
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Hummel, Micheal (författare)
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Sixta, Herbert (författare)
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- Mikkola, Jyri-Pekka (författare)
- Umeå universitet,Kemiska institutionen,Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University
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(creator_code:org_t)
- Elsevier, 2014
- 2014
- Engelska.
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Ingår i: Biomass and Bioenergy. - : Elsevier. - 0961-9534 .- 1873-2909. ; 70, s. 373-381
- Relaterad länk:
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http://www.sciencedi...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Abstract Improved fractionation process conditions for wood dissolution with switchable ionic liquids (SILs) were determined. The short time, high temperature (STHT) system was introduced as a selective and efficient way to extract components from lignocellulosic material. A SIL based on monoethanol amine (MEA) and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU) formed via coupling with SO2, was applied as a solvent in a 1:3 weight ratio with water. In essence, selective dissolution of mainly lignin was achieved by means of the aqueous SIL at 160 °C (∼6.1 bar corresponding to the vapor pressure of water) in 2 h and in a pressure vessel, for both hard- and soft-wood. About 95 wt-% of wood lignin was extracted. The dissolved components in the spent SIL were recovered by the addition of an anti-solvent whereupon over 70% of the dissolved components were recovered; the recovered fraction contained 19 wt-% hemicellulose while the rest of the material was in essence lignin. The non-dissolved, fluffy material contained ∼70 wt-% cellulose and ∼20 wt-% hemicellulose – a consistency resembling that of Kraft pulp.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Switchable ionic liquids
- Optimal selective fractionation of lignin
- Hardwood
- Softwood
- Gel permeation chromatography (GPC)
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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