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Structural Requirem...
Structural Requirements for the Thallium(III)‑mediated Cyclisation of Unsaturated Alcohols : A Novel Fragmentation Reaction Producing 19‑Norsteroids
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- Kocovsky, Pavel (författare)
- UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN
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- Langer, Vratislaw (författare)
- CHALMERS UNIV TECHNOL, DEPT INORGAN CHEM, S-41296 GOTHENBURG, SWEDEN
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- Gogoll, Adolf, 1957- (författare)
- Uppsala universitet,Organisk kemi I
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(creator_code:org_t)
- 1990
- 1990
- Engelska.
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Ingår i: Journal of the Chemical Society. Chemical communications. - 0022-4936. ; 15, s. 1028-1028
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The unsaturated alcohol (1) is readily cyclised to the hydroxytetrahydrofuran (3) by means of thallium(III), whereas its congener (4) has been found to give (7) as the product of a novel, stereoelectronically controlled, fragmentation; the scope of the tandem electrophilic cyclisation/solvolysis is discussed; the structure of (7) has been determined by X-ray crystallography.
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