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Photoinduced desorp...
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Hellsing, BChalmers University of Technology
(författare)
Photoinduced desorption of potassium atoms from graphite
- Artikel/kapitelEngelska1996
Förlag, utgivningsår, omfång ...
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Elsevier BV,1996
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:uu-235941
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-235941URI
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https://doi.org/10.1016/0039-6028(96)00144-6DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:ref swepub-contenttype
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Ämneskategori:art swepub-publicationtype
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We present an experimental and theoretical investigation of desorption of potassium atoms from the basal plane of graphite induced by photons with energies from 2 to 6 eV. The intensity of the photon flux employed in the measurements is low, and the observed photodesorption is a single-photon, non-thermal event. At monolayer coverage the photon-energy dependence of the cross section has a maximum at 4.8 eV. The experimental observations are interpreted in terms of a hot carrier mechanism, which involves attachment of optically excited substrate hot electrons to the empty 4s state of ionized potassium, and then desorption. The theory predicts a Gaussian line shape of the photoyield versus photon energy. Fitting the model parameters to the experimental data, we determine: (i) the potential energy for Gr + K+ and Gr + K-0; and (ii) the position (2.4 eV above the Fermi level) and width (0.15 eV) of the potassium 4s resonance, which is in good agreement with independent experimental observations.
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Biuppslag (personer, institutioner, konferenser, titlar ...)
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Chakarov, D VChalmers University of Technology
(författare)
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Österlund, Lars,1967-Uppsala universitet,Fasta tillståndets fysik(Swepub:uu)laros288
(författare)
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Zhdanov, V PChalmers University of Technology
(författare)
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Kasemo, BChalmers University of Technology
(författare)
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Chalmers University of TechnologyFasta tillståndets fysik
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Surface Science: Elsevier BV363:1-3, s. 247-2510039-60281879-2758
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