PHOTOSTIMULATED DESORPTION OF METAL ADATOMS - POTASSIUM ON GRAPHITE

Photodesorption is observed of single K atoms from a graphite surface covered with less than 1 monolayer of potassium. The desorption cross section has a threshold at homegaBAR almost-equal-to 3 eV and a maximum at homega(max)BAR almost-equal-to 4.9 eV. Polarization measurements indicate a substrate-mediated mechanism. The coverage dependence suggests that only the ionic 2D, K-phase is photoactive. The proposed mechanism includes attachment of hot electrons, photoexcited in the bulk, to the K4s adsorbate resonance of energy E(res). The band structure of graphite causes a narrow energy distribution of hot electrons, which yields homega(max)BAR almost-equal-to 2E(res).

Österlund, Lars,1967-Uppsala universitet,Fasta tillståndets fysik(Swepub:uu)laros288 (författare)
HELLSING, BChalmers University of Technology (författare)
ZHDANOV, VPChalmers University of Technology (författare)
KASEMO, BChalmers University of Technology (författare)
Chalmers University of TechnologyFasta tillståndets fysik (creator_code:org_t)

Av författaren/redakt...: CHAKAROV, DV; Österlund, Lars, ...; HELLSING, B; ZHDANOV, VP; KASEMO, B

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