Sökning: onr:"swepub:oai:DiVA.org:uu-302691" >
Diindeno-fusion of ...
-
Rudebusch, Gabriel E.Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA.;Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA.
(författare)
Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals
- Artikel/kapitelEngelska2016
Förlag, utgivningsår, omfång ...
-
2016-05-23
-
Springer Science and Business Media LLC,2016
-
printrdacarrier
Nummerbeteckningar
-
LIBRIS-ID:oai:DiVA.org:uu-302691
-
https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-302691URI
-
https://doi.org/10.1038/nchem.2518DOI
Kompletterande språkuppgifter
-
Språk:engelska
-
Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
-
Ämneskategori:ref swepub-contenttype
-
Ämneskategori:art swepub-publicationtype
Anmärkningar
-
The consequence of unpaired electrons in organic molecules has fascinated and confounded chemists for over a century. The study of open-shell molecules has been rekindled in recent years as new synthetic methods, improved spectroscopic techniques and powerful computational tools have been brought to bear on this field. Nonetheless, it is the intrinsic instability of the biradical species that limits the practicality of this research. Here we report the synthesis and characterization of a molecule based on the diindeno[b,i]anthracene framework that exhibits pronounced open-shell character yet possesses remarkable stability. The synthetic route is rapid, efficient and possible on the gram scale. The molecular structure was confirmed through single-crystal X-ray diffraction. From variable-temperature Raman spectroscopy and magnetic susceptibility measurements a thermally accessible triplet excited state was found. Organic field-effect transistor device data show an ambipolar performance with balanced electron and hole mobilities. Our results demonstrate the rational design and synthesis of an air-and temperature-stable biradical compound.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
-
Zafra, Jose L.Univ Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(författare)
-
Jorner, KjellUppsala universitet,Institutionen för kemi - BMC(Swepub:uu)kjejo447
(författare)
-
Fukuda, KotaroOsaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan.
(författare)
-
Marshall, Jonathan L.Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA.;Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA.
(författare)
-
Arrechea-Marcos, IratxeUniv Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(författare)
-
Espejo, Guzman L.Univ Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(författare)
-
Ponce Ortiz, RocioUniv Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(författare)
-
Gomez-Garcia, Carlos J.Univ Valencia, Inst Ciencia Mol, Valencia 46980, Spain.
(författare)
-
Zakharov, Lev N.Univ Oregon, CAMCOR, Eugene, OR 97403 USA.
(författare)
-
Nakano, MasayoshiOsaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan.
(författare)
-
Ottosson, HenrikUppsala universitet,Institutionen för kemi - BMC(Swepub:uu)heott255
(författare)
-
Casado, JuanUniv Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(författare)
-
Haley, Michael M.Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA.;Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA.
(författare)
-
Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA.;Univ Oregon, Inst Mat Sci, Eugene, OR 97403 USA.Univ Malaga, Dept Phys Chem, Campus Teatinos S-N, Malaga 229071, Spain.
(creator_code:org_t)
Sammanhörande titlar
-
Ingår i:Nature Chemistry: Springer Science and Business Media LLC8:8, s. 753-7591755-43301755-4349
Internetlänk
Hitta via bibliotek
Till lärosätets databas
- Av författaren/redakt...
-
Rudebusch, Gabri ...
-
Zafra, Jose L.
-
Jorner, Kjell
-
Fukuda, Kotaro
-
Marshall, Jonath ...
-
Arrechea-Marcos, ...
-
visa fler...
-
Espejo, Guzman L ...
-
Ponce Ortiz, Roc ...
-
Gomez-Garcia, Ca ...
-
Zakharov, Lev N.
-
Nakano, Masayosh ...
-
Ottosson, Henrik
-
Casado, Juan
-
Haley, Michael M ...
-
visa färre...
- Om ämnet
-
- NATURVETENSKAP
-
NATURVETENSKAP
-
och Kemi
- Artiklar i publikationen
-
Nature Chemistry
- Av lärosätet
-
Uppsala universitet