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Self-Assembly of Sq...
Self-Assembly of Square-Planar Halide Complexes of Trimethylphosphine-Stabilized Diphenyl-Arsenium, -Stibenium, and -Bismuthenium Hexafluorophosphates*
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Wielandt, J. Wolfram (författare)
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Petrie, Simon (författare)
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Kilah, Nathan L. (författare)
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Willis, Anthony C. (författare)
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Dewhurst, Rian D. (författare)
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Belaj, Ferdinand (författare)
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- Orthaber, Andreas (författare)
- Uppsala universitet,Molekylär biomimetik
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Stranger, Robert (författare)
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Wild, S. Bruce (författare)
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(creator_code:org_t)
- 2016
- 2016
- Engelska.
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Ingår i: Australian Journal of Chemistry. ; 69:5, s. 524-532
- Relaterad länk:
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http://www.publish.c...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Square-planar halide complexes in which four trimethylphosphine-stabilized diphenyl-stibenium or -bismuthenium ions surround a central halide ion in discrete centrosymmetrical structures of C4h symmetry have been isolated and their structures determined by X-ray crystallography. The structures are stabilized by electrostatic interactions between the halide ion and four positively charged trimethylphosphine-stabilized diphenyl-stibenium or -bismuthenium ions, as well as four edge-to-face phenyl–phenyl embraces above and below the plane containing the nine main group elements. The parent halide-free trimethylphosphine-stabilized diphenyl-arsenium, -stibenium, and -bismuthenium hexaflurophosphate complexes have also been prepared and structurally characterized.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
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