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How the Negative El...
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Björklund, ErikUppsala universitet,Strukturkemi
(författare)
How the Negative Electrode Influences Interfacial and Electrochemical Properties of LiNi1/3Co1/3Mn1/3O2 Cathodes in Li-Ion Batteries
- Artikel/kapitelEngelska2017
Förlag, utgivningsår, omfång ...
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2017-10-07
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The Electrochemical Society,2017
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electronicrdacarrier
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LIBRIS-ID:oai:DiVA.org:uu-338161
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-338161URI
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https://doi.org/10.1149/2.0711713jesDOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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The cycle life of LiNi1/3Co1/3Mn1/3O2 (NMC) based cells are significantly influenced by the choice of the negative electrode. Electrochemical testing and post mortem surface analysis are here used to investigate NMC electrodes cycled vs. either Li-metal, graphite or Li4Ti5O12 (LTO) as negative electrodes. While NMC-LTO and NMC-graphite cells show small capacity fading over 200 cycles, NMC-Li-metal cell suffers from rapid capacity fading accompanied with an increased voltage hysteresis despite the almost unlimited access of lithium. X-ray absorption near edge structure (XANES) results show that no structural degradation occurs on the positive electrode even after >200 cycles, however, X-ray photoelectron spectroscopy (XPS) results shows that the composition of the surface layer formed on the NMC cathode in the NMC-Li-metal cell is largely different from that of the other NMC cathodes (cycled in the NMC-graphite or NMC-LTO cells). Furthermore, it is shown that the surface layer thickness on NMC increases with the number of cycles, caused by continuous electrolyte degradation products formed at the Li-metal negative electrode and then transferred to NMC positive electrode.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Brandell, Daniel,1975-Uppsala universitet,Strukturkemi(Swepub:uu)dbr10334
(författare)
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Hahlin, MariaUppsala universitet,Molekyl- och kondenserade materiens fysik(Swepub:uu)mahed424
(författare)
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Edström, Kristina,Professor,1958-Uppsala universitet,Strukturkemi(Swepub:uu)ked02526
(författare)
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Younesi, RezaUppsala universitet,Strukturkemi(Swepub:uu)rezyo975
(författare)
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Uppsala universitetStrukturkemi
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Journal of the Electrochemical Society: The Electrochemical Society164:13, s. A3054-A30590013-46511945-7111
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