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Metal-water covalen...
Metal-water covalency in the photo-aquated ferrocyanide complex as seen by multi-edge picosecond X-ray absorption
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- Vaz da Cruz, Vinicius (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.
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- Mascarenhas, Eric J. (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.;Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany.
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- Buechner, Robby (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.;Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany.
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- Jay, Raphael M. (författare)
- Uppsala universitet,Kemisk och biomolekylär fysik,Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
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- Fondell, Mattis (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.
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- Eckert, Sebastian (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.
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- Foehlisch, Alexander (författare)
- Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.;Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany.
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Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany Helmholtz Zent Berlin Materialien & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Res, D-12489 Berlin, Germany.;Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany. (creator_code:org_t)
- 2022
- 2022
- Engelska.
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Ingår i: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry. - 1463-9076 .- 1463-9084. ; 24:45, s. 27819-27826
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https://uu.diva-port... (primary) (Raw object)
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- In this work, we investigate the photo-aquation reaction of the ferrocyanide anion with multi-edge picosecond soft X-ray spectroscopy. Combining the information of the iron L-edge with nitrogen and oxygen K-edges, we carry out a complete characterization of the bonding channels in the [Fe(CN)(5)(H2O)](3-) photo-product. We observe clear spectral signatures of covalent bonding between water and the metal, reflecting the mixing of the Fe d(z)(2) orbital with the 3a(1) and 4a(1) orbitals of H2O. Additional fingerprints related to the symmetry reduction and the resulting loss in orbital degeneracy are also reported. The implications of the elucidated fingerprints in the context of future ultra-fast experiments are also discussed.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
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