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Conductivity in Thi...
Conductivity in Thin Films of Transition Metal Coordination Complexes
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- Spinelli, Giovanni (författare)
- Newcastle Univ, Sch Nat & Environm Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England.
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- Morritt, George H. (författare)
- Newcastle Univ, Sch Math Stat & Phys, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England.
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- Pavone, Michele (författare)
- Univ Naples Federico II, Dept Chem Sci, I-80126 Naples, Italy.
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- Probert, Michael R. (författare)
- Newcastle Univ, Sch Nat & Environm Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England.
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- Waddel, Paul G. (författare)
- Newcastle Univ, Sch Nat & Environm Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England.
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- Edvinsson, Tomas, Professor, 1970- (författare)
- Uppsala universitet,Fasta tillståndets fysik
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- Munoz-Garcia, Ana Belen (författare)
- Univ Naples Federico II, Dept Phys Ettore Pancini, I-80126 Naples, Italy.
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- Freitag, Marina (författare)
- Newcastle Univ, Sch Nat & Environm Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England.
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Newcastle Univ, Sch Nat & Environm Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England Newcastle Univ, Sch Math Stat & Phys, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England. (creator_code:org_t)
- 2023-02-06
- 2023
- Engelska.
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Ingår i: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 6:4, s. 2122-2127
- Relaterad länk:
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Two coordination complexes have been made by combining the dithiolene complexes [M(mnt)(2)](2-) (mnt = maleonitriledithiolate; M = Ni2+ or Cu2+) as anion, with the copper(II) coordination complex [Cu(Stetra)] (Stetra = 6,6 ' - bis(4,5-dihydrothiazol-2-yl)-2,2 ' -bipyri-dine) as cation. The variation of the metal centers leads to a dramatic change in the conductivity of the materials, with the M = Cu2+ variant (Cu-Cu) displaying semiconductor behavior with a conductivity of approximately 2.5 x 10(-8) S cm(-1), while the M = Ni2+ variant (Ni-Cu) displayed no observable conductivity. Computational studies found Cu-Cu enables a minimization of reorganization energy losses and, as a result, a lower barrier to the charge transfer process, resulting in the reported higher conductivity.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Nyckelord
- charge transfer
- electrical conductivity
- energy materials
- coordination complexes
- copper complexes
- charge transfer materials
- salts
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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